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Research Article

Hierarchical porous molybdenum carbide synergic morphological engineering towards broad multi-band tunable microwave absorption

Tianbao Zhao1,2, Di Lan1( ), Zirui Jia3, Zhenguo Gao2, Guanglei Wu2( )
School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan 442002, China
Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China
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Graphical Abstract

Multiple Schottky barriers and interfacial polarization exist between two-dimensional (2D) MoS2 and zero-dimensional (0D) Mo2C, and between 2D MoS2 and three-dimensional (3D) hierarchical porous carbon, and more importantly, impedance matching is optimized.

Abstract

With the accelerating development of electronic technology, how to effectively eliminate electromagnetic radiation pollution has become a critical issue. Electromagnetic wave (EMW) absorption materials have an irreplaceable position in the field of military stealth as well as in the field of electromagnetic pollution control. In order to cope with the complicated electromagnetic environment, the design of multifunctional and multiband high-efficiency EMW absorbers remains a daunting challenge. In this work, a hierarchical porous molybdenum carbide matrix with a three-dimensional porous structure was designed by salt melt synthesis (SMS) strategy. Furthermore, the relationship between the structure and the impedance matching performance was explored by stepwise modification via ultrathin layered MoS2 nanoflakes. Analysis indicates that the extent of modification of hierarchical porous molybdenum carbide by MoS2 nanoflakes modulates the dielectric performance due to differences in morphology and the introduction of heterogeneous structures, along with a dramatic impact on the impedance matching performance. In particular, the prepared MS/MC/PNC-2 composite exhibits a reflection loss (RL) of −55.30 dB at 2.4 mm, and an ultra-broad effective absorption bandwidth (EAB) of 7.60 GHz is obtained at 2.0 mm. The coordination of structure and component enables the absorber to exhibit strong absorption, wide bandwidth, thin thickness, and multi-band absorption characteristics. Noticeably, the effective absorption performance in the broadband for X and Ku is also satisfying, as well as possessing moderate marine anti-corrosion performance. This study contributes to an in-depth understanding of the relationship between impedance matching and EMW absorber performance and provides a reference for the design of multifunctional, multiband microwave absorbing materials.

Keywords

electromagnetic wave absorberimpedance matchingmultibandSchottky barrier

Electronic Supplementary Material

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Nano Research
Volume 17 Issue 11,
November 2024
Pages 9845-9856
DOI: 10.1007/s12274-024-6938-1
Cite this article:
Zhao T, Lan D, Jia Z, et al. Hierarchical porous molybdenum carbide synergic morphological engineering towards broad multi-band tunable microwave absorption. Nano Research, 2024, 17(11): 9845-9856. https://doi.org/10.1007/s12274-024-6938-1
Topics:
Carbon compositesMolybdenum compoundsNanostructured materialsNanostructures

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Received: 15 July 2024
Revised: 31 July 2024
Accepted: 03 August 2024
Published: 12 September 2024
© Tsinghua University Press 2024
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