AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

Hierarchical porous molybdenum carbide synergic morphological engineering towards broad multi-band tunable microwave absorption

Tianbao Zhao1,2, Di Lan1( ), Zirui Jia3, Zhenguo Gao2, Guanglei Wu2( )
School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan 442002, China
Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China
Show Author Information

Graphical Abstract

Multiple Schottky barriers and interfacial polarization exist between two-dimensional (2D) MoS2 and zero-dimensional (0D) Mo2C, and between 2D MoS2 and three-dimensional (3D) hierarchical porous carbon, and more importantly, impedance matching is optimized.

Abstract

With the accelerating development of electronic technology, how to effectively eliminate electromagnetic radiation pollution has become a critical issue. Electromagnetic wave (EMW) absorption materials have an irreplaceable position in the field of military stealth as well as in the field of electromagnetic pollution control. In order to cope with the complicated electromagnetic environment, the design of multifunctional and multiband high-efficiency EMW absorbers remains a daunting challenge. In this work, a hierarchical porous molybdenum carbide matrix with a three-dimensional porous structure was designed by salt melt synthesis (SMS) strategy. Furthermore, the relationship between the structure and the impedance matching performance was explored by stepwise modification via ultrathin layered MoS2 nanoflakes. Analysis indicates that the extent of modification of hierarchical porous molybdenum carbide by MoS2 nanoflakes modulates the dielectric performance due to differences in morphology and the introduction of heterogeneous structures, along with a dramatic impact on the impedance matching performance. In particular, the prepared MS/MC/PNC-2 composite exhibits a reflection loss (RL) of −55.30 dB at 2.4 mm, and an ultra-broad effective absorption bandwidth (EAB) of 7.60 GHz is obtained at 2.0 mm. The coordination of structure and component enables the absorber to exhibit strong absorption, wide bandwidth, thin thickness, and multi-band absorption characteristics. Noticeably, the effective absorption performance in the broadband for X and Ku is also satisfying, as well as possessing moderate marine anti-corrosion performance. This study contributes to an in-depth understanding of the relationship between impedance matching and EMW absorber performance and provides a reference for the design of multifunctional, multiband microwave absorbing materials.

Keywords

electromagnetic wave absorberimpedance matchingmultibandSchottky barrier

Electronic Supplementary Material

Download File(s)
6938_ESM.pdf (1.3 MB)

References

[1]

Zhong, X.; He, M. K.; Zhang, C. Y.; Guo, Y. Q.; Hu, J. W.; Gu, J. W. Heterostructured BN@Co-C@C endowing polyester composites excellent thermal conductivity and microwave absorption at C band. Adv. Funct. Mater. 2024, 34, 2313544.
Crossref Google Scholar
[2]

Qiao, J.; Song, Q. H.; Zhang, X.; Zhao, S. Y.; Liu, J. R.; Nyström, G.; Zeng, Z. H. Enhancing interface connectivity for multifunctional magnetic carbon aerogels: An in situ growth strategy of metal-organic frameworks on cellulose nanofibrils. Adv. Sci. 2024, 11, 2400403.
Crossref Google Scholar
[3]

Liu, P. B.; Zheng, S. Y.; He, Z. Z.; Qu, C.; Zhang, L. Q.; Ouyang, B.; Wu, F.; Kong, J. Optimizing integrated-loss capacities via asymmetric electronic environments for highly efficient electromagnetic wave absorption. Small 2024, 20, 2403903.
Crossref Google Scholar
[4]

Jia, R. X.; Zhang, R.; Yu, L. B.; Kong, X. L.; Bao, S. C.; Tu, M. Y.; Liu, X. H.; Xu, B. H. Engineering a hierarchical carbon supported magnetite nanoparticles composite from metal organic framework and graphene oxide for lithium-ion storage. J. Colloid Interface Sci. 2023, 630, 86–98.
Crossref Google Scholar
[5]

Yan, J.; Ye, Z. D.; Lan, D.; Chen, W. X.; Jia, Z. R.; Wu, G. L. Transition metal carbides towards electromagnetic wave absorption application: State of the art and perspectives. Compos. Commun. 2024, 48, 101954.
Crossref Google Scholar
[6]
Su, X. G.; Wang, J.; Liu, T.; Zhang, Y.; Liu, Y. N.; Zhang, B.; Liu, Y. Q.; Wu, H. J.; Xu, H. X. Controllable atomic migration in microstructures and defects for electromagnetic wave absorption enhancement. Adv. Funct. Mater., in press, DOI: 10.1002/adfm.202403397.
[7]
Qiao, J.; Song, Q. H.; Xuan, L. X.; Liu, J. R.; Zhang, X.; Zheng, S. N.; Lin, J. P.; Cai, W. Q.; Zhang, Q. D.; Zeng, Z. H. et al. Dual cross-linked magnetic MXene aerogel with high strength and durability enables multifunctionality. Adv. Funct. Mater., in press, DOI: 10.1002/adfm.202401687.
[8]

Ma, G. J.; Lan, D.; Zhang, Y.; Sun, X. Y.; Jia, Z. R.; Wu, G. L.; Bu, G. X.; Yin, P. F. Microporous cobalt ferrite with bio-carbon loosely decorated to construct multi-functional composite for dye adsorption, anti-bacteria and electromagnetic protection. Small 2024, 20, 2404449.
Crossref Google Scholar
[9]

Yang, X.; Xuan, L. X.; Men, W. W.; Wu, X.; Lan, D.; Shi, Y. P.; Jia, H. X.; Duan, Y. P. Carbonyl iron/glass fiber cloth composites: Achieving multi-spectrum stealth in a wide temperature range. Chem. Eng. J. 2024, 491, 151862.
Crossref Google Scholar
[10]

Li, B.; Tian, H. Y.; Li, L.; Liu, W.; Liu, J. R.; Zeng, Z. H.; Wu, N. Graphene-assisted assembly of electrically and magnetically conductive ceramic nanofibrous aerogels enable multifunctionality. Adv. Funct. Mater. 2024, 34, 2314653.
Crossref Google Scholar
[11]
He, M. K.; Hu, J. W.; Yan, H.; Zhong, X.; Zhang, Y. L.; Liu, P. B.; Kong, J.; Gu, J. W. Shape anisotropic chain-like CoNi/polydimethylsiloxane composite films with excellent low-frequency microwave absorption and high thermal conductivity. Adv. Funct. Mater., in press, DOI: 10.1002/adfm.202316691.
[12]

Chen, X. L.; Zhang, F.; Lan, D.; Zhang, S. J.; Du, S. X.; Zhao, Z. W.; Ji, G. B.; Wu, G. L. State-of-the-art synthesis strategy for nitrogen-doped carbon-based electromagnetic wave absorbers: From the perspective of nitrogen source. Adv. Compos. Hybrid Mater. 2023, 6, 220.
Crossref Google Scholar
[13]

Pan, F.; Shi, Y. Y.; Yang, Y.; Guo, H. T.; Li, L. X.; Jiang, H. J.; Wang, X.; Zeng, Z. H.; Lu, W. Porifera-inspired lightweight, thin, wrinkle-resistance, and multifunctional MXene foam. Adv. Mater. 2024, 36, 2311135.
Crossref Google Scholar
[14]

Han, Y.; Han, M. J.; Zhao, T. B.; Xia, Z. H.; Zou, J. X.; Liu, X. H.; Jia, Z. R. Design of morphology-controlled cobalt-based spinel oxides for efficient X-band microwave absorption. Mater. Res. Bull. 2024, 172, 112670.
Crossref Google Scholar
[15]

Feng, A. L.; Zhu, X.; Chen, Y. N.; Liu, P. T.; Han, F. B.; Zu, Y. Q.; Li, X. D.; Bi, P. F. Functional biomass-derived materials for the development of sustainable batteries. ChemElectroChem 2024, 11, e202400086.
Crossref Google Scholar
[16]

Lian, Y. Y.; Lan, D.; Jiang, X. D.; Wang, L.; Yan, S.; Dong, Q. Z.; Jiang, Y.; Gu, J. W.; Gao, Z. G.; Wu, G. L. Multifunctional electromagnetic wave absorbing carbon fiber/Ti3C2T X MXene fabric with superior near-infrared laser dependent photothermal antibacterial behaviors. J. Colloid Interface Sci. 2024, 676, 217–226.
Crossref Google Scholar
[17]

Zhang, X.; Tian, X. L.; Wu, N.; Zhao, S. Y.; Qin, Y. T.; Pan, F.; Yue, S. Y.; Ma, X. Y.; Qiao, J.; Xu, W. et al. Metal-organic frameworks with fine-tuned interlayer spacing for microwave absorption. Sci. Adv. 2024, 10, eadl6498.
Crossref Google Scholar
[18]

Zeng, J. Q.; Qi, P. F.; Wang, Y.; Liu, Y. H.; Sui, K. Y. Electrostatic assembly construction of polysaccharide functionalized hybrid membrane for enhanced antimony removal. J. Hazard. Mater. 2021, 410, 124633.
Crossref Google Scholar
[19]

Zheng, T. T.; Zhang, Y.; Jia, Z. R.; Zhu, J. H.; Wu, G. L.; Yin, P. F. Customized dielectric-magnetic balance enhanced electromagnetic wave absorption performance in Cu x S/CoFe2O4 composites. Chem. Eng. J. 2023, 457, 140876.
Crossref Google Scholar
[20]
Jia, Z. R.; Liu, J. K.; Gao, Z. G.; Zhang, C. H.; Wu, G. L. Molecular intercalation-induced two-phase evolution engineering of 1T and 2H-MS2 (M = Mo, V, W) for interface-polarization-enhanced electromagnetic absorbers. Adv. Funct. Mater., in press, DOI: 10.1002/adfm.202405523.
[21]
Xiao, J. X.; Zhan, B. B.; He, M. K.; Qi, X. S.; Gong, X.; Yang, J. L.; Qu, Y. P.; Ding, J. F.; Zhong, W.; Gu, J. W. Interfacial polarization loss improvement induced by the hollow engineering of necklace-like PAN/carbon nanofibers for boosted microwave absorption. Adv. Funct. Mater., in press, DOI: 10.1002/adfm.202316722.
[22]

Lan, D.; Hu, Y.; Wang, M.; Wang, Y.; Gao, Z. G.; Jia, Z. R. Perspective of electromagnetic wave absorbing materials with continuously tunable effective absorption frequency bands. Compos. Commun. 2024, 50, 101993.
Crossref Google Scholar
[23]

Liu, J. L.; Liang, H. S.; Zhang, Y.; Wu, G. L.; Wu, H. J. Facile synthesis of ellipsoid-like MgCo2O4/Co3O4 composites for strong wideband microwave absorption application. Compos. Part B: Eng. 2019, 176, 107240.
Crossref Google Scholar
[24]

Cao, X. L.; Lan, D.; Zhang, Y.; Jia, Z. R.; Wu, G. L.; Yin, P. F. Construction of three-dimensional conductive network and heterogeneous interfaces via different ratio for tunable microwave absorption. Adv. Compos. Hybrid Mater. 2023, 6, 187.
Crossref Google Scholar
[25]

Zhang, Y. L.; Ruan, K. P.; Zhou, K.; Gu, J. W. Controlled distributed Ti3C2T x hollow microspheres on thermally conductive polyimide composite films for excellent electromagnetic interference shielding. Adv. Mater. 2023, 35, 2211642.
Crossref Google Scholar
[26]
Han, M. J.; Lan, D.; Zhang, Z. M.; Zhao, Y. Z.; Zou, J. X.; Gao, Z. G.; Wu, G. L.; Jia, Z. R. Micro-sized hexapod-like CuS/Cu9S5 hybrid with broadband electromagnetic wave absorption. J. Mater. Sci. Technol., in press, DOI: 10.1016/j.jmst.2024.07.014.
[27]

Hong, Y.; Liu, Y.; Wu, J. Z.; Li, Y.; Wu, X. H. Enhanced tunability of broadband microwave absorption for MoSe2/FeSe2 nanocomposites with a unique heterostructure. Ind. Eng. Chem. Res. 2022, 61, 5807–5815.
Crossref Google Scholar
[28]
Han, Y.; Lan, D.; Han, M. J.; Xia, Z. H.; Zou, J. X.; Jia, Z. R. Construction of flower-like MoS2 decorated on Cu doped CoZn-ZIF derived N-doped carbon as superior microwave absorber. Nano Res. 2024, 17, 8250–8260.
[29]

Yang, J. M.; Wang, H.; Zhang, Y. L.; Zhang, H. X.; Gu, J. W. Layered structural PBAT composite foams for efficient electromagnetic interference shielding. Nano-Micro Lett. 2024, 16, 31.
Crossref Google Scholar
[30]

Zhou, Z. H.; Zhou, X. F.; Lan, D.; Zhang, Y.; Jia, Z. R.; Wu, G. L.; Yin, P. F. Modulation engineering of electromagnetic wave absorption performance of layered double hydroxides derived hollow metal carbides integrating corrosion protection. Small 2024, 20, 2305849.
Crossref Google Scholar
[31]

Fu, X. Y.; Zheng, Q.; Li, L.; Cao, M. S. Vertically implanting MoSe2 nanosheets on the RGO sheets towards excellent multi-band microwave absorption. Carbon 2022, 197, 324–333.
Crossref Google Scholar
[32]
Zhang, S. J.; Lan, D.; Zheng, J. J.; Chen, X. L.; Feng, A. L.; Pei, Y. X.; Cai, S. C.; Du, S. X.; Wu, G. L.; Jia, Z. R. Rational construction of heterointerfaces in biomass sugarcane-derived carbon for superior electromagnetic wave absorption. Int. J. Miner. Metall. Mater., in press, DOI: 10.1007/s12613-024-2875-y.
[33]

Wan, Y. C.; Zheng, M. Y.; Lv, R. T. Rational design of Mo2C nanosheets anchored on hierarchically porous carbon for boosting electrocatalytic N2 reduction to NH3. Mater. Today Energy 2023, 32, 101240.
Crossref Google Scholar
[34]

Liu, X. F.; Fechler, N.; Antonietti, M. Salt melt synthesis of ceramics, semiconductors and carbon nanostructures. Chem. Soc. Rev. 2013, 42, 8237–8265.
Crossref Google Scholar
[35]
Xie, X. B.; Wang, H. S.; Kimura, H.; Ni, C.; Du, W.; Wu, G. L. NiCoZn/C@melamine sponge-derived carbon composites with high-performance electromagnetic wave absorption. Int. J. Miner. Metall. Mater., in press, DOI: 10.1007/s12613-024-2880-1.
[36]

Gong, K. J.; Peng, Y. M.; Liu, A.; Qi, S. H.; Qiu, H. Ultrathin carbon layer coated MXene/PBO nanofiber films for excellent electromagnetic interference shielding and thermal stability. Compos. Part A: Appl. Sci. Manuf. 2024, 176, 107857.
Crossref Google Scholar
[37]

Ma, T. B.; Zhang, Y. L.; Ruan, K. P.; Guo, H.; He, M. K.; Shi, X. T.; Guo, Y. Q.; Kong, J.; Gu, J. W. Advances in 3D printing for polymer composites: A review. InfoMat 2024, 6, e12568.
Crossref Google Scholar
[38]

Liu, P. B.; Gao, S.; Wang, Y.; Zhou, F. T.; Huang, Y.; Luo, J. H. Metal-organic polymer coordination materials derived Co/N-doped porous carbon composites for frequency-selective microwave absorption. Compos. Part B: Eng. 2020, 202, 108406.
Crossref Google Scholar
[39]

Feng, A. L.; Liu, L.; Liu, P. T.; Zu, Y. Q.; Han, F. B.; Li, X. D.; Ding, S. J.; Chen, Y. N. Interfacial nanoparticles of Co2P/Co3Fe7 encapsulated in N-doped carbon nanotubes as bifunctional oxygen electrocatalysts for rechargeable zinc-air batteries. Mater. Today Energy 2024, 44, 101626.
Crossref Google Scholar
[40]

Wei, C. H.; Shi, L. Z.; Li, M. Q.; He, M. K.; Li, M. J.; Jing, X. R.; Liu, P. B.; Gu, J. W. Hollow engineering of sandwich NC@Co/NC@MnO2 composites toward strong wideband electromagnetic wave attenuation. J. Mater. Sci. Technol. 2024, 175, 194–203.
Crossref Google Scholar
[41]

Li, J. J.; Lan, D.; Cheng, Y. H.; Jia, Z. R.; Liu, P. B.; Shi, X. T.; Guo, H.; Feng, A. L.; Feng, X.; Wu, G. L. et al. Constructing mixed-dimensional lightweight magnetic cobalt-based composites heterostructures: An effective strategy to achieve boosted microwave absorption and self-anticorrosion. J. Mater. Sci. Technol. 2024, 196, 60–70.
Crossref Google Scholar
[42]

Sun, M. X.; Wang, D. R.; Xiong, Z. M.; Zhang, Z. W.; Qin, L.; Chen, C. C.; Wu, F.; Liu, P. B. Multi-dimensional Ni@C-CoNi composites with strong magnetic interaction toward superior microwave absorption. J. Mater. Sci. Technol. 2022, 130, 176–183.
Crossref Google Scholar
[43]

Zhao, T. B.; Jia, Z. R.; Liu, J. K.; Zhang, Y.; Wu, G. L.; Yin, P. F. Multiphase interfacial regulation based on hierarchical porous molybdenum selenide to build anticorrosive and multiband tailorable absorbers. Nano-Micro Lett. 2024, 16, 6.
Crossref Google Scholar
[44]

Liu, J. K.; Jia, Z. R.; Dong, Y. H.; Li, J. J.; Cao, X. L.; Wu, G. L. Structural engineering and compositional manipulation for high-efficiency electromagnetic microwave absorption. Mater. Today Phys. 2022, 27, 100801.
Crossref Google Scholar
[45]

Yuan, M. Y.; Lv, H. L.; Cheng, H. W.; Zhao, B.; Chen, G. Y.; Zhang, J. C.; Che, R. C. Atomic and electronic reconstruction in defective 0D molybdenum carbide heterostructure for regulating lower-frequency microwaves. Adv. Funct. Mater. 2023, 33, 2302003.
Crossref Google Scholar
[46]

Feng, A. L.; Lan, D.; Liu, J. K.; Wu, G. L.; Jia, Z. R. Dual strategy of A-site ion substitution and self-assembled MoS2 wrapping to boost permittivity for reinforced microwave absorption performance. J. Mater. Sci. Technol. 2024, 180, 1–11.
Crossref Google Scholar
[47]

Hao, H. C.; Wang, Y. X.; Katyal, N.; Yang, G.; Dong, H.; Liu, P. C.; Hwang, S.; Mantha, J.; Henkelman, G.; Xu, Y. X. et al. Molybdenum carbide electrocatalyst in situ embedded in porous nitrogen-rich carbon nanotubes promotes rapid kinetics in sodium-metal-sulfur batteries. Adv. Mater. 2022, 34, 2106572.
Crossref Google Scholar
[48]

Kim, S.; Choi, C.; Hwang, J.; Park, J.; Jeong, J.; Jun, H.; Lee, S.; Kim, S. K.; Jang, J. H.; Jung, Y. et al. Interaction mediator assisted synthesis of mesoporous molybdenum carbide: Mo-valence state adjustment for optimizing hydrogen evolution. ACS Nano 2020, 14, 4988–4999.
Crossref Google Scholar
[49]

Bai, R.; Yan, W. F.; Xiao, Y.; Wang, S. Q.; Tian, X. C.; Li, J. P.; Xiao, X. F.; Lu, X. Q.; Zhao, F. Acceleration of peroxymonosulfate decomposition by a magnetic MoS2/CuFe2O4 heterogeneous catalyst for rapid degradation of fluoxetine. Chem. Eng. J. 2020, 397, 125501.
Crossref Google Scholar
[50]

Zhao, T. B.; Jia, Z. R.; Zhang, Y.; Wu, G. L. Multiphase molybdenum carbide doped carbon hollow sphere engineering: The superiority of unique double-shell structure in microwave absorption. Small 2023, 19, 2206323.
Crossref Google Scholar
[51]

Zhang, X. C.; Zhang, X.; Yuan, H. R.; Li, K. Y.; Ouyang, Q. Y.; Zhu, C. L.; Zhang, S.; Chen, Y. J. CoNi nanoparticles encapsulated by nitrogen-doped carbon nanotube arrays on reduced graphene oxide sheets for electromagnetic wave absorption. Chem. Eng. J. 2020, 383, 123208.
Crossref Google Scholar
[52]

Bai, S.; Li, X. Y.; Kong, Q.; Long, R.; Wang, C. M.; Jiang, J.; Xiong, Y. J. Toward enhanced photocatalytic oxygen evolution: Synergetic utilization of plasmonic effect and Schottky junction via interfacing facet selection. Adv. Mater. 2015, 27, 3444–3452.
Crossref Google Scholar
[53]

Lee, S. Y.; Kim, U. J.; Chung, J.; Nam, H.; Jeong, H. Y.; Han, G. H.; Kim, H.; Oh, H. M.; Lee, H.; Kim, H. et al. Large work function modulation of monolayer MoS2 by ambient gases. ACS Nano 2016, 10, 6100–6107.
Crossref Google Scholar
[54]

Lang, Q. Q.; Chen, Y. H.; Huang, T. L.; Yang, L. N.; Zhong, S. X.; Wu, L. J.; Chen, J. R.; Bai, S. Graphene “bridge” in transferring hot electrons from plasmonic Ag nanocubes to TiO2 nanosheets for enhanced visible light photocatalytic hydrogen evolution. Appl. Catal. B: Environ. 2018, 220, 182–190.
Crossref Google Scholar
[55]

Du, J. F.; Shen, Y. L.; Yang, F.; Zhang, B.; Jiang, X. Z.; An, C. H.; Ye, J. H. In situ construction of an α-MoC/g-C3N4 Mott-Schottky heterojunction with high-speed electron transfer channel for efficient photocatalytic H2 evolution. Inorg. Chem. Front. 2023, 10, 832–840.
Crossref Google Scholar
[56]

Pajkossy, T.; Jurczakowski, R. Electrochemical impedance spectroscopy in interfacial studies. Curr. Opin. Electrochem. 2017, 1, 53–58.
Crossref Google Scholar
[57]

Yin, P. F.; Lan, D.; Lu, C. F.; Jia, Z. R.; Feng, A. L.; Liu, P. B.; Shi, X. T.; Guo, H.; Wu, G. L.; Wang, J. Research progress of structural regulation and composition optimization to strengthen absorbing mechanism in emerging composites for efficient electromagnetic protection. J. Mater. Sci. Technol. 2025, 204, 204–223.
Crossref Google Scholar
[58]
Zhang, F.; Li, N.; Shi, J. F.; Wang, Y. Y.; Yan, D. X.; Li, Z. M. Cation bimetallic MOF anchored carbon fiber for highly efficient microwave absorption. Small, in press, DOI: 10.1002/smll.202312135.
[59]

Zhou, J. X.; Huang, X. M.; Lan, D.; Cheng, Y. H.; Xue, F. Y.; Jia, C. Y.; Wu, G. L.; Jia, Z. R. Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization. Nano Res. 2024, 17, 2050–2060.
Crossref Google Scholar
[60]

Tan, D. L.; Wang, Q.; Li, M. R.; Song, L. M.; Zhang, F.; Min, Z. Y.; Wang, H. L.; Zhu, Y. Q.; Zhang, R.; Lan, D. et al. Magnetic media synergistic carbon fiber@ Ni/NiO composites for high-efficiency electromagnetic wave absorption. Chem. Eng. J. 2024, 492, 152245.
Crossref Google Scholar
[61]

Liu, Y.; Zhou, X. F.; Jia, Z. R.; Wu, H. J.; Wu, G. L. Oxygen vacancy-induced dielectric polarization prevails in the electromagnetic wave-absorbing mechanism for Mn-based MOFs-derived composites. Adv. Funct. Mater. 2022, 32, 2204499.
Crossref Google Scholar
[62]

Liu, P. B.; Gao, S.; Liu, X. D.; Huang, Y.; He, W. J.; Li, Y. T. Rational construction of hierarchical hollow CuS@CoS2 nanoboxes with heterogeneous interfaces for high-efficiency microwave absorption materials. Compos. Part B: Eng. 2020, 192, 107992.
Crossref Google Scholar
[63]

Gao, Z. G.; Lan, D.; Ren, X. Y.; Jia, Z. R.; Wu, G. L. Manipulating cellulose-based dual-network coordination for enhanced electromagnetic wave absorption in magnetic porous carbon nanocomposites. Compos. Commun. 2024, 48, 101922.
Crossref Google Scholar
[64]

Zhang, F.; Li, N.; Shi, J. F.; Xu, L.; Jia, L. C.; Wang, Y. Y.; Yan, D. X. Recent progress on carbon-based microwave absorption materials for multifunctional applications: A review. Compos. Part B: Eng. 2024, 283, 111646.
Crossref Google Scholar
[65]

Zhang, Q. L.; Lan, D.; Deng, S. L.; Gu, J. W.; Wang, Y. Q.; Ren, J. W.; Wu, G. L.; Jia, Z. R. Constructing multiple heterogeneous interfaces in one-dimensional carbon fiber materials for superior electromagnetic wave absorption. Carbon 2024, 226, 119233.
Crossref Google Scholar
[66]

Su, X. G.; Zhang, Y.; Wang, J.; Liu, Y. Q. Enhanced electromagnetic wave absorption and mechanical performances of graphite nanosheet/PVDF foams via ice dissolution and normal pressure drying. J. Mater. Chem. C 2024, 12, 7775–7783.
Crossref Google Scholar
[67]

Dong, Y. H.; Lan, D.; Xu, S.; Gu, J. W.; Jia, Z. R.; Wu, G. L. Controllable fiberization engineering of cobalt anchored mesoporous hollow carbon spheres for positive feedback to electromagnetic wave absorption. Carbon 2024, 228, 119339.
Crossref Google Scholar
[68]

He, Y. F.; Su, Q.; Liu, D. D.; Xia, L.; Huang, X. X.; Lan, D.; Liu, Y. N.; Huang, Y. D.; Zhong, B. Surface engineering strategy for MXene to tailor electromagnetic wave absorption performance. Chem. Eng. J. 2024, 491, 152041.
Crossref Google Scholar
[69]

Huang, X. M.; Liu, X. H.; Zhang, Y.; Zhou, J. X.; Wu, G. L.; Jia, Z. R. Construction of NiCeO x nanosheets-skeleton cross-linked by carbon nanotubes networks for efficient electromagnetic wave absorption. J. Mater. Sci. Technol. 2023, 147, 16–25.
Crossref Google Scholar
[70]
Zheng, S. N.; Xu, W. L.; Liu, J. R.; Pan, F.; Zhao, S. Y.; Wang, Y. D.; Zeng, Z. H.; Wu, N. One-hour ambient-pressure-dried, scalable, stretchable MXene/polyurea aerogel enables synergistic defense against high-frequency mechanical shock and electromagnetic waves. Adv. Funct. Mater., in press, DOI: 10.1002/adfm.202402889.
[71]

Hao, Z. W.; Zhou, J.; Lin, S. N.; Lan, D.; Li, H. Y.; Wang, H.; Liu, D.; Gu, J. W.; Wang, X. B.; Wu, G. L. Customized heterostructure of transition metal carbides as high-efficiency and anti-corrosion electromagnetic absorbers. Carbon 2024, 228, 119323.
Crossref Google Scholar
[72]

Wen, J. H.; Lan, D.; Wang, Y. Q.; Ren, L. G.; Feng, A. L.; Jia, Z. R.; Wu, G. L. Absorption properties and mechanism of lightweight and broadband electromagnetic wave-absorbing porous carbon by the swelling treatment. Int. J. Miner. Metall. Mater. 2024, 31, 1701–1712.
Crossref Google Scholar
[73]

Wu, N. N.; Zhao, B. B.; Lian, Y. Y.; Liu, S. S.; Xian, Y.; Gu, J. W.; Wu, G. L. Metal organic frameworks derived Ni x Se y @NC hollow microspheres with modifiable composition and broadband microwave attenuation. Carbon 2024, 226, 119215.
Crossref Google Scholar
[74]

Chen, X. L.; Lan, D.; Zhou, L. T.; Zeng, Z.; Liu, Y. K.; Du, S. X.; Zou, Z. Y.; Wu, G. L. Rational construction of ZnFe2O4 decorated hollow carbon cloth towards effective electromagnetic wave absorption. Ceram. Int. 2024, 50, 24549–24557.
Crossref Google Scholar
[75]

Shen, Z. Y.; Lan, D.; Cong, Y.; Lian, Y. Y.; Wu, N. N.; Jia, Z. R. Tailored heterogeneous interface based on porous hollow In-Co-C nanorods to construct adjustable multi-band microwave absorber. J. Mater. Sci. Technol. 2024, 181, 128–137.
Crossref Google Scholar
[76]

Lan, D.; Li, H. F.; Wang, M.; Ren, Y. J.; Zhang, J.; Zhang, M. Q.; Ouyang, L. X.; Tang, J.; Wang, Y. Y. Recent advances in construction strategies and multifunctional properties of flexible electromagnetic wave absorbing materials. Mater. Res. Bull. 2024, 171, 112630.
Crossref Google Scholar
[77]

Zhang, S. J.; Lan, D.; Chen, X. L.; Gu, Y. Y.; Ren, J. W.; Du, S. X.; Cai, S. C.; Zhao, X. M.; Zhao, Z. W.; Wu, G. L. Three-dimensional macroscopic absorbents: From synergistic effects to advanced multifunctionalities. Nano Res. 2024, 17, 1952–1983.
Crossref Google Scholar
[78]

Lv, H. L.; Yao, Y. X.; Li, S. C.; Wu, G. L.; Zhao, B.; Zhou, X. D.; Dupont, R. L.; Kara, U. I.; Zhou, Y. M.; Xi, S. B. et al. Staggered circular nanoporous graphene converts electromagnetic waves into electricity. Nat. Commun. 2023, 14, 1982.
Crossref Google Scholar
[79]

Lv, H. L.; Yang, Z. H.; Liu, B.; Wu, G. L.; Lou, Z. C.; Fei, B.; Wu, R. B. A flexible electromagnetic wave-electricitiy harvester. Nat. Commun. 2021, 12, 834.
Crossref Google Scholar
[80]

Zhou, J. X.; Lan, D.; Zhang, F.; Cheng, Y. H.; Jia, Z. R.; Wu, G. L.; Yin, P. F. Self-assembled MoS2 cladding for corrosion resistant and frequency-modulated electromagnetic wave absorption materials from X-band to Ku-band. Small 2023, 19, 2304932.
Crossref Google Scholar
[81]

Liang, L. L.; Liu, Z.; Xie, L. J.; Chen, J. P.; Jia, H.; Kong, Q. Q.; Sun, G. H.; Chen, C. M. Bamboo-like N-doped carbon tubes encapsulated CoNi nanospheres towards efficient and anticorrosive microwave absorbents. Carbon 2021, 171, 142–153.
Crossref Google Scholar
[82]

Li, X. D.; Zhu, X.; Feng, A. L.; An, M. M.; Liu, P. T.; Zu, Y. Q. Electrochemical and surface analysis investigation of corrosion inhibition performance: 6-Thioguanine, benzotriazole, and phosphate salt on simulated patinas of bronze relics. J. Mater. Res. Technol. 2024, 29, 5667–5680.
Crossref Google Scholar
Nano Research
Volume 17 Issue 11,
November 2024
Pages 9845-9856
DOI: 10.1007/s12274-024-6938-1
Cite this article:
Zhao T, Lan D, Jia Z, et al. Hierarchical porous molybdenum carbide synergic morphological engineering towards broad multi-band tunable microwave absorption. Nano Research, 2024, 17(11): 9845-9856. https://doi.org/10.1007/s12274-024-6938-1
Topics:
Carbon compositesMolybdenum compoundsNanostructured materialsNanostructures

501

Views

30

Crossref

30

Web of Science

32

Scopus

0

CSCD

Altmetrics
Received: 15 July 2024
Revised: 31 July 2024
Accepted: 03 August 2024
Published: 12 September 2024
© Tsinghua University Press 2024
Return