Graphical Abstract
![](https://wqketang.oss-cn-beijing.aliyuncs.com/zip-unzip/zip-34bcd421-2eee-44b0-939e-7cd86ef6ac71/101237TH-2024-7-1434/files/101237TH-2024-7-1434-gab.jpg?Expires=1725755413&OSSAccessKeyId=STS.NUNrx7UMJz4hQQXWC1h3rdYSp&Signature=AKxHhLMPuZibmMveutXXNwFPS7U%3D&security-token=CAISywJ1q6Ft5B2yfSjIr5b7OcKDuJJrzfaDU3fps0NkZLxei5z4kjz2IHtKenhsBOsbtfk1mG5W5%2FgZlqJ9SptIAEfJa9d99MybfrZDltCT1fau5Jko1beHewHKeTOZsebWZ%2BLmNqC%2FHt6md1HDkAJq3LL%2Bbk%2FMdle5MJqP%2B%2FUFB5ZtKWveVzddA8pMLQZPsdITMWCrVcygKRn3mGHdfiEK00he8TouufTinpHMskGA1Aell7Mvyt6vcsT%2BXa5FJ4xiVtq55utye5fa3TRYgxowr%2Fwo0v0YpGya5YzHXwcPskvdKZbo78UqLQlla6w%2BGqFJqvPxr%2Fp8t%2Fx5fWJKAezhVgs8cVM8JOjIqKOscIsiBmxs7AWPcD1LXoQ6vH1ZZ5%2FAzVZaVWUEMpNqcRxTMldXaQqhSZT8m3upKXzOJeX7ls9%2Fv%2FV7p8MZuo7UTzDnGoABFWkbnwnXWJnbmyet8fNq1LK%2Bo5i19G0TKS1upb2ojPIRD9fHSfEybtjVZCtT%2BRSUSA6dKZUIAhKOwQh2pUKCHaUgDc5z%2Bjvd3U3AGuvCOLDm7ZJ4V6HFro6ZvN2Fh%2Fmy5%2Fxr%2Fpk6MpkaCskP0lGzZTpciR50lVg%2BDl%2FC65RQaBQgAA%3D%3D)
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Extensive efforts have been made to pursue a low-friction state with promising applications in many fields, such as mechanical and biomedical engineering. Among which, the load capacity of the low-friction state has been considered to be crucial for industrial applications. Here, we report a low friction under ultrahigh contact pressure by building a novel self-assembled fluorinated azobenzene layer on an atomically smooth highly-oriented pyrolytic graphite (HOPG) surface. Sliding friction coefficients could be as low as 0.0005 or even lower under a contact pressure of up to 4 GPa. It demonstrates that the low friction under ultrahigh contact pressure is attributed to molecular fluorination. The fluorination leads to effective and robust lubrication between the tip and the self-assembled layer and enhances tighter rigidity which can reduce the stress concentration in the substrate, which was verified by density functional theory (DFT) and molecular dynamics (MD) simulation. This work provides a new approach to avoid the failure of ultralow friction coefficient under relatively high contact pressure, which has promising potential application value in the future.
281
Views
11
Downloads
1
Crossref
2
Web of Science
2
Scopus
0
CSCD
Altmetrics
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.
The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.
To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.