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Research Article | Open Access

Unconventional piezoelectric coefficients in perovskite piezoelectric ceramics

Jingen Wua, Zhongqiang Hua( ), Xiangyu Gaoa, Miaomiao Chenga, Xinger Zhaoa, Wei Sua, Liqian Wanga, Mengmeng Guana, Yongjun Dua, Ruohao Maoa, Zhiguang Wanga, Ziyao Zhoua, Shuxiang Dongb, Ming Liua( )
Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education & International Center for Dielectric Research, School of Electronic Science and Engineering, State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an, 710049, China
Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing, 100871, China

Peer review under responsibility of The Chinese Ceramic Society.

Show Author Information

Highlights

• A “rotated poling” method is proposed to realize unconventional piezoelectric coefficients in piezoelectric ceramics.

• Full nonzero piezoelectric cofficients in the 3 × 6 piezoelectric coefficients matrix can be obtained.

• We demonstrate a promising way to expanding the diversity of piezoelectric devices.

Graphical Abstract

Abstract

Piezoelectric ceramics exhibit three conventional piezoelectric coefficients, i.e., d33, d31, d15, due to their crystal symmetry. Unconventional piezoelectric coefficients, such as d11, d12, d13, d14, d16, etc., can only be extracted from piezoelectric single crystals of special symmetry with specific cut direction. Here we demonstrate a rotated poling method to realize unconventional piezoelectric coefficients in perovskite piezoelectric ceramics. This method is elaborated in theory and experimentally proven to be effective. Full nonzero piezoelectric coefficients in the 3 × 6 piezoelectric coefficients matrix can be obtained by combining these “quasi (effective) piezoelectric coefficients” with the conventional piezoelectric coefficients, which would expand applications in a wide variety of piezoelectric devices.

Keywords

Quasi piezoelectric coefficientsDiversity of piezoelectric devicesPerovskite structure

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Journal of Materiomics
Volume 7 Issue 2,
March 2021
Pages 254-263
DOI: 10.1016/j.jmat.2020.10.004
Cite this article:
Wu J, Hu Z, Gao X, et al. Unconventional piezoelectric coefficients in perovskite piezoelectric ceramics. Journal of Materiomics, 2021, 7(2): 254-263. https://doi.org/10.1016/j.jmat.2020.10.004

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Received: 30 July 2020
Revised: 15 September 2020
Accepted: 18 October 2020
Published: 21 October 2020
© 2021 The Chinese Ceramic Society.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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