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The continuous development of the global energy structure transformation has put forward higher demands upon the development of batteries. The improvements of the energy density have become one of the important indicators and hot topic for novel secondary batteries. The energy density of existing lithium-ion battery has encountered a bottleneck due to the limitations of material and systems. Herein, this paper introduces the concept and development of multi-electron reaction materials over the past twenty years. Guided by the multi-electron reaction, light weight electrode and multi-ion effect, current development strategies and future trends of high-energy-density batteries are highlighted from the perspective of materials and structure system innovation. Typical cathode and anode materials with the multi-electron reactions are summarized from cation-redox to anion-redox, from intercalation-type to alloying-type, and from liquid systems to solid-state lithium batteries. The properties of the typical materials and their engineering prospects are comprehensively discussed, and additionally, the application potential and the main challenges currently encountered by solid-state batteries are also introduced. Finally, this paper gives a comprehensive outlook on the development of high-energy-density batteries.
Yang Y S. A review of electrochemical energy storage researches in the past 22 years[J]. J. Electrochem., 2020, 26: 443-463
Rudola A, Wright C J, Barker J. Reviewing the safe shipping of lithium-ion and sodium-ion cells: A materials chemistry perspective[J]. Energy Mater. Adv., 2021, 2021: 9798460
Li W J, Xu H Y, Yang Q, Li J M, Zhang Z Y, Wang S B, Peng J Y, Zhang B, Chen X L, Zhang Z, Yang M, Zhao Y, Geng Y Y, Huang W S, Ding Z P, Zhang L, Tian Q Y, Yu H G, Li H. Development of strategies for high-energy-density lithium batteries[J]. Energy Storage Sci. Technol., 2020, 9: 448-478
Gao M D, Li H, Xu L, Xue Q, Wang X N, Bai Y, Wu C. Lithium metal batteries for high energy density: Fundamental electrochemistry and challenges[J]. J. Energy Chem., 2021, 59: 666-687.
Shen Y B, Zhang Y T, Han S J, Wang J W, Peng Z Q, Chen L W. Unlocking the energy capabilities of lithium metal electrode with solid-state electrolytes[J]. Joule, 2018, 2(9): 1674-1689.
Wang X R, Tan G Q, Bai Y, Wu F, Wu C. Multi-electron reaction materials for high-energy-density secondary batteries: current status and prospective[J]. Electrochem. Energy Rev., 2021, 4(1): 35-66.
Zhang C Z, Liu Z, Wu F, Lin L J, Qi F. Electrochemical generation of ferrate on SnO2-Sb2O3/Ti electrodes in strong concentration basic condition[J]. Electrochem. Commun., 2004, 6(11): 1104-1109.
Jung C H, Shim H, Eum D, Hong S H. Challenges and recent progress in LiNixCoyMn1-x-yO2 (NCM) cathodes for lithium ion batteries[J]. J. Korean Ceram. Soc., 2021, 58(1): 1-27.
Sun H H, Choi W, Lee J K, Oh I H, Jung H G. Control of electrochemical properties of nickel-rich layered cathode materials for lithium ion batteries by variation of the manganese to cobalt ratio[J]. J. Power Sources, 2015, 275: 877-883.
Wang L F, Wang R, Wang J Y, Xu R, Wang X D, Zhan C. Nanowelding to improve the chemomechanical stability of the Ni-rich layered cathode materials[J]. ACS Appl. Mater. Interfaces, 2021, 13(7): 8324-8336.
Noh H J, Chen Z, Yoon C S, Lu J, Amine K, Sun Y K. Cathode material with nanorod structure an application for advanced high-energy and safe lithium batteries[J]. Chem. Mater., 2013, 25(10): 2109-2115.
Zhang J C, Yang Z Z, Gao R, Gu L, Hu Z B, Liu X F. Suppressing the structure deterioration of Ni-rich LiNi0.8Co0.1Mn0.1O2 through atom-scale interfacial integration of self-forming hierarchical spinel layer with Ni gradient concentration[J]. ACS Appl. Mater. Interfaces, 2017, 9(35): 29794-29803.
Jiang M, Danilov D L, Eichel R A, Notten P H L. A review of degradation mechanisms and recent achievements for Ni-rich cathode-based Li-ion batteries[J]. Adv. Energy Mater., 2021, 11(48): 2103005.
Zhao H C, Bai Y, Jin H F, Zhou J, Wang X R, Wu C. Unveiling thermal decomposition kinetics of single-crystalline Ni-rich LiNi0.88Co0.07Mn0.05O2 cathode for safe lithium-ion batteries[J]. Chem. Eng. J., 2022, 435: 134927.
Yu H J, Zhou H S. High-energy cathode materials (Li2MnO3-LiMO2) for lithium-ion batteries[J]. J. Phys. Chem. Lett., 2013, 4(8): 1268-1280.
Johnson C S, Li N, Lefief C, Thackeray M M. Anomalous capacity and cycling stability of xLi2MnO3·(1-x)LiMO2 electrodes (M = Mn, Ni, Co) in lithium batteries at 50 ℃[J]. Electrochem. Commun., 2007, 9(4): 787-795.
Gu M, Belharouak I, Zheng J, Wu H, Xiao J, Genc A, Amine K, Thevuthasan S, Baer D R, Zhang J G. Formation of the spinel phase in the layered composite cathode used in Li-ion batteries[J]. ACS Nano, 2013, 7(1): 760-767.
Hu S L, Li Y, Chen Y H, Peng J M, Zhou T F, Pang W K, Didier C, Peterson V K, Wang H Q, Li Q Y, Guo Z P. Insight of a phase compatible surface coating for long-durable Li-rich layered oxide cathode[J]. Adv. Energy Mater., 2019, 9(34): 1901795.
Yu R Z, Banis M N, Wang C H, Wu B, Huang Y, Cao S, Li J J, Jamil S, Lin X T, Zhao F P, Lin W H, Chang B B, Yang X K, Huang H, Wang X Y, Sun X L. Tailoring bulk Li+ ion diffusion kinetics and surface lattice oxygen activity for high-performance lithium-rich manganese-based layered oxides[J]. Energy Storage Mater., 2021, 37: 509-520
Zuo Y X, Li B A, Jiang N, Chu W S, Zhang H, Zou R Q, Xia D G. A high-capacity O2-type Li-rich cathode material with a single-layer Li2MnO3 superstructure[J]. Adv. Mater., 2018, 30(16): 1707255.
Wang Z K, Li Y, Ji H Q, Zhou J Q, Qian T, Yan C L. Unity of opposites between soluble and insoluble lithium polysulfides in lithium-sulfur batteries[J]. Adv. Mater., 2022: 2203699
Yuan K G, Wang A B, Cao G P, Yang Y S. Preparation and electrochemical performance of a novel lithium battery cathode material polysulfurpolyaniline[J]. Chem. J. Chinese U., 2005, 26(11):2117-2119
Wang M J, Wang W K, Wang A B, Yuan K G, Miao L X, Zhang X L, Huang Y Q, Yu Z B, Qiu J Y. A multi-core-shell structured composite cathode material with a conductive polymer network for Li-S batteries[J]. Chem. Commun., 2013, 49(87): 10263-10265.
Zhao C R, Wang W K, Yu Z B, Zhang H, Wang A B, Yang Y S. Nano-CaCO3 as template for preparation of disordered large mesoporous carbon with hierarchical porosities[J]. J. Mater. Chem., 2010, 20(5): 976-980.
Yu Z B, Wang W K, Wang A B, Yuan K G, Yang Y S. Effect of electrolyte on electrochemical performance of sulfur electrode[J]. Battery Bimon., 2006, 36(1): 3-4
Wang W K, Yu Z B, Yuan K G, Wang A B, Yang Y S. Key materials of high energy lithium sulfur batteries[J]. Prog. Chem., 2011, 23(2-3): 540-547
Ge M, Cao C, Biesold G M, Sewell C D, Hao S M, Huang J, Zhang W, Lai Y, Lin Z. Recent advances in silicon-based electrodes: from fundamental research toward practical applications[J]. Adv. Mater., 2021, 33(16): 2004577.
Chan C K, Peng H L, Liu G, McIlwrath K, Zhang X F, Huggins R A, Cui Y. High-performance lithium battery anodes using silicon nanowires[J]. Nat. Nanotechnol., 2008, 3(1): 31-35.
Chen S, Shen L, van Aken P A, Maier J, Yu Y. Dual-fun-ctionalized double carbon shells coated silicon nanoparticles for high performance lithium-ion batteries[J]. Adv. Mater., 2017, 29(21): 1605650.
Zhang J G, Xu W, Xiao J, Cao X, Liu J. Lithium metal anodes with nonaqueous electrolytes[J]. Chem. Rev., 2020, 120(24): 13312-13348.
Liu Y, Huang S B, Meng Q Q, Fan Y C, Wang B Y, Yang Y S, Cao G P, Zhang H. In-situ growth of Ag particles anchored Cu foam scaffold for dendrite-free lithium metal anode[J]. J. Alloy. Compd., 2021, 885: 160882.
Meng Q Q, Deng B, Zhang H M, Wang B Y, Zhang W F, Wen Y H, Ming H, Zhu X Y, Guan Y P, Xiang Y, Li M, Cao G P, Yang Y S, Peng H L, Zhang H, Huang Y Q. Heterogeneous nucleation and growth of electrodeposited lithium metal on the basal plane of single-layer graphene[J]. Energy Storage Mater., 2019, 16: 419-425
Zhang R, Chen X, Shen X, Zhang X Q, Chen X R, Cheng X B, Yan C, Zhao C Z, Zhang Q. Coralloid carbon fiber-based composite lithium anode for robust lithium metal batteries[J]. Joule, 2018, 2(4): 764-777.
Zhang K, Wu F, Zhang K, Weng S T, Wang X R, Gao M D, Sun Y H, Cao D, Bai Y, Xu H J, Wang X F, Wu C. Chlorinated dual-protective layers as interfacial stabilizer for dendrite-free lithium metal anode[J]. Energy Storage Mater., 2021, 41: 485-494
Gao H, Grundish N S, Zhao Y, Zhou A, Goodenough J B. Formation of stable interphase of polymer-in-salt electrolyte in all-solid-state lithium batteries[J]. Energy Mater. Adv., 2021, 2021: 1932952
Wu F, Zhang K, Liu Y R, Gao H C, Bai Y, Wang X R, Wu C. Polymer electrolytes and interfaces toward solid-state batteries: recent advances and prospects[J]. Energy Storage Mater., 2020, 33: 26-54
Zhang K, Wu F, Wang X R, Zheng L M, Yang X Y, Zhao H C, Sun Y H, Zhao W B, Bai Y, Wu C A. An ion-dipole-reinforced polyether electrolyte with ion-solvation cages enabling high-voltage-tolerant and ion-conductive solid-state lithium metal batteries[J]. Adv. Funct. Mater., 2022, 32(5): 2107764.
Zhang K, Wu F, Wang X R, Weng S T, Yang X Y, Zhao H C, Guo R Q, Sun Y H, Zhao W B, Song T L, Wang X F, Bai Y, Wu C. 8.5 μm-thick flexible-rigid hybrid solid-electrolyte/lithium integration for air-stable and interface-compatible all-solid-state lithium metal batteries[J]. Adv. Energy Mater., 2022, 12(24): 2200368.
Cheng S H S, Liu C, Zhu F Y, Zhao L, Fan R, Chung C Y, Tang J N, Zeng X R, He Y B. (Oxalato)borate: The key ingredient for polyethylene oxide based composite electrolyte to achieve ultra-stable performance of high voltage solid-state LiNi0.8Co0.1Mn0.1O2/lithium metal battery[J]. Nano Energy, 2021, 80: 105562.
Liu Y J, He P, Zhou H S. Rechargeable solid-state Li-air and Li-S batteries: materials, construction, and challenges[J]. Adv. Energy Mater., 2018, 8(4): 1701602.
Li S M, Chen Z F, Zhang W T, Li S N, Pan F. High-thro-ughput screening of protective layers to stabilize the electrolyte-anode interface in solid-state Li-metal batteries[J]. Nano Energy, 2022, 102: 107640.
Guo Q Y, Xu F L, Shen L, Deng S G, Wang Z Y, Li M Q, Yao X Y. 20 μm-thick Li6.4La3Zr1.4Ta0.6O12-based flexible solid electrolytes for all-solid-state lithium batteries[J]. Energy Mater. Adv., 2022: 9753506
Zhu L, Wang Y M, Wu Y M, Feng W L, Liu Z L, Tang W P, Wang X W, Xia Y Y. Boron nitride-based release agent coating stabilizes Li1.3Al0.3Ti1.7(PO4)3/Li interface with superior lean-lithium electrochemical performance and thermal stability[J]. Adv. Funct. Mater., 2022, 32(29): 2201136.
Wu J H, Liu S F, Han F D, Yao X Y, Wang C S. Lithium/sulfide all-solid-state batteries using sulfide electroly-tes[J]. Adv. Mater., 2021, 33(6): 2000751.
Nikodimos Y, Huang C J, Taklu B W, Su W N, Hwang B J. Chemical stability of sulfide solid-state electrolytes: Stability toward humid air and compatibility with solvents and binders[J]. Energy Environ. Sci., 2022, 15: 991-1033.
Zhang Q, Cao D X, Ma Y, Natan A, Aurora P, Zhu H L. Sulfide-based solid-state electrolytes: synthesis, stability, and potential for all-solid-state batteries[J]. Adv. Mater., 2019, 31(44): 1901131.
Lee J, Lee T, Char K, Kim K J, Choi J W. Issues and advances in scaling up sulfide-based all-solid-state batteries[J]. Accounts. Chem. Res., 2021, 54(17): 3390-3402.
Sun N, Song Y J, Liu Q S, Zhao W, Zhang F, Ren L P, Chen M, Zhou Z N, Xu Z H, Lou S F. Surface-to-bulk synergistic modification of single crystal cathode enables stable cycling of sulfide-based all-solid-state batteries at 4.4 V[J]. Adv. Energy Mater., 2022, 12(29): 2200682.
Liang Y H, Liu H, Wang G X, Wang C, Ni Y, Nan C W, Fan L Z. Challenges, interface engineering, and processing strategies toward practical sulfide-based all-solid-state lithium batteries[J]. InfoMat, 2022, 4(5): e12292
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