AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Energy Materials and Devices Article
PDF (12.3 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

ZnS/CuS nanoparticles encapsulated in multichannel carbon fibers as high-performance anode materials for flexible Li-ion capacitors

Bohan Li1, Chong Wang1, Zhouyang Qin1, Chenhui Luan3, Changzhen Zhan1, Liangliang Li1, Ruitao Lv1,2, Wanci Shen1, Zheng-Hong Huang1,2( )
Key Laboratory of Advanced Materials (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
Show Author Information

Graphical Abstract

Abstract

Transition metal sulfides (TMSs) are widely recognized for their potential as anode materials in the development of flexible lithium-ion capacitors (FLICs) owing to their high theoretical capacity. However, their practical application has been significantly limited by rapid capacity decay and sluggish kinetics associated with TMS volume variation. In response to these challenges, we have prepared ZnS/CuS nanoparticles embedded in continuous and multichannel carbon fibers (CFs). This was achieved through a process involving blow-spinning and subsequent sulfidation. Notably, the electrochemical performance of these materials was largely improved, owing to the synergistic effect of bimetallic sulfides. The ZnS/CuS-CF anode material demonstrated a high specific capacity of over 900 mAh g−1 at a current density of 0.2 A g−1. Furthermore, it exhibited superior rate capacity (300 mAh g−1 at 20 A g−1) and excellent cyclic stability, maintaining its performance over 1000 cycles at 10 A g−1. We also prepared lithium-ion capacitors (LICs) using the same method. These LICs exhibited a maximum energy density of 136 Wh kg−1, a high power density of 43.5 kW kg−1, and an impressive cyclic stability over 4000 cycles. In addition, the FLICs, when configured in the form of a pouch cell, demonstrated significant potential for the development of smart, flexible electronic devices.

Keywords

metal sulfidesanodecarbon fiberflexiblelithium-ion capacitors

Electronic Supplementary Material

Download File(s)
EMD-2023-0012_ESM.pdf (15.1 MB)

References

[1]

Li, B. L., Yu, M., Li, Z. S., Yu, C. L., Wang, H. Q., Li, Q. Y. (2022). Constructing flexible all-solid-state supercapacitors from 3D nanosheets active bricks via 3D manufacturing technology: A perspective review. Adv. Funct. Mater. 32, 2201166.
Crossref Google Scholar
[2]

Asl, M. S., Hadi, R., Salehghadimi, L., Tabrizi, A. G., Farhoudian, S., Babapoor, A., Pahlevani, M. (2022). Flexible all-solid-state supercapacitors with high capacitance, long cycle life, and wide operational potential window: Recent progress and future perspectives. J. Energy Storage 50, 104223.
Crossref Google Scholar
[3]

Ma, J., Kong, Y., Liu, S. C., Li, Y. T., Jiang, J. B., Zhou, Q. Y., Huang, Y. S., Han, S. (2020). Flexible phosphorus-doped graphene/metal-organic framework-derived porous Fe2O3 anode for lithium-ion battery. ACS Appl. Energy Mater. 3, 11900–11906.
Crossref Google Scholar
[4]

Gao, L., Wu, G. S., Ma, J., Jiang, T. C., Chang, B., Huang, Y. S., Han, S. (2020). SnO2 quantum dots@graphene framework as a high-performance flexible anode electrode for lithium-ion batteries. ACS Appl. Mater. Interfaces 12, 12982–12989.
Crossref Google Scholar
[5]

Zhang, M., Li, L. H., Jian, X. L., Zhang, S., Shang, Y. Y., Xu, T. T., Dai, S. G., Xu, J. M., Kong, D. Z., Wang, Y., et al. (2021). Free-standing and flexible CNT/(Fe@Si@SiO2) composite anodes with kernel-pulp-skin nanostructure for high-performance lithium-ion batteries. J. Alloys Compd. 878, 160396.
Crossref Google Scholar
[6]

Que, L. F., Yu, F. D., Wang, Z. B., Gu, D. M. (2018). Pseudocapacitance of TiO2−x/CNT anodes for high-performance quasi-solid-state Li-ion and Na-ion capacitors. Small 14, 1704508.
Crossref Google Scholar
[7]

Le, T., Tian, H., Cheng, J., Huang, Z. H., Kang, F. Y., Yang, Y. (2018). High performance lithium-ion capacitors based on scalable surface carved multi-hierarchical construction electrospun carbon fibers. Carbon 138, 325–336.
Crossref Google Scholar
[8]

Shi, R. Y., Han, C. P., Xu, X. F., Qin, X. Y., Xu, L., Li, H. F., Li, J. Q., Wong, C. P., Li, B. H. (2018). Electrospun N-doped hierarchical porous carbon nanofiber with improved degree of graphitization for high-performance lithium ion capacitor. Chem. Eur. J. 24, 10460–10467.
Crossref Google Scholar
[9]

Shi, J. J., Wang, S. L., Wang, Q., Chen, X., Du, X. Y., Wang, M., Zhao, Y. J., Dong, C., Ruan, L. M., Zeng, W. (2020). A new flexible zinc-ion capacitor based on δ-MnO2@Carbon cloth battery-type cathode and MXene@Cotton cloth capacitor-type anode. J. Power Sources 446, 227345.
Crossref Google Scholar
[10]

Zhu, C. Y., Ye, Y. W., Guo, X., Cheng, F. (2022). Design and synthesis of carbon-based nanomaterials for electrochemical energy storage. New Carbon Mater. 37, 59–92.
Crossref Google Scholar
[11]

Zhao, J. B., Zhang, Y. Y., Wang, Y. H., Li, H., Peng, Y. Y. (2018). The application of nanostructured transition metal sulfides as anodes for lithium ion batteries. J. Energy Chem. 27, 1536–1554.
Crossref Google Scholar
[12]

Lu, S. J., Wang, Z. T., Zhang, X. H., He, Z. J., Tong, H., Li, Y. J., Zheng, J. C. (2020). In situ-formed hollow cobalt sulfide wrapped by reduced graphene oxide as an anode for high-performance lithium-ion batteries. ACS Appl. Mater. Interfaces 12, 2671–2678.
Crossref Google Scholar
[13]

Hou, T. Y., Liu, B. R., Sun, X. H., Fan, A. R., Xu, Z. K., Cai, S., Zheng, C. M., Yu, G. H., Tricoli, A. (2021). Covalent coupling-stabilized transition-metal sulfide/carbon nanotube composites for lithium/sodium-ion batteries. ACS Nano 15, 6735–6746.
Crossref Google Scholar
[14]

Hou, Z. D., Jiang, M. W., Cao, Y. J., Liu, H. Y., Zhang, Y., Wang, J. G. (2022). Encapsulating ultrafine cobalt sulfides into multichannel carbon nanofibers for superior Li-ion energy storage. J. Power Sources 541, 231682.
Crossref Google Scholar
[15]

Zhou, X. H., Su, K. M., Kang, W. M., Cheng, B. W., Li, Z. H., Jiang, Z. (2020). Locking metal sulfide nanoparticles in interconnected porous carbon nanofibers with protective macro-porous skin as freestanding anodes for lithium ion batteries. Chem. Eng. J. 397, 125271.
Crossref Google Scholar
[16]

Xu, H. Z., Sun, L., Li, W., Gao, M. Y., Zhou, Q. N., Li, P., Yang, S. K., Lin, J. J. (2022). Facile synthesis of hierarchical g-C3N4@WS2 composite as lithium-ion battery anode. Chem. Eng. J. 435, 135129.
Crossref Google Scholar
[17]

Cai, Y. Q., Liu, H. G., Li, H. R., Sun, Q. Z., Wang, X., Zhu, F. Y., Li, Z. Q., Kim, J. K., Huang, Z. D. (2023). Strong coordination interaction in amorphous Sn-Ti-ethylene glycol compound for stable Li-ion storage. Energy Mater. Devices 1, 9370013.
Crossref Google Scholar
[18]

Fang, Y. J., Luan, D. Y., Lou, X. W. (2020). Recent advances on mixed metal sulfides for advanced sodium-ion batteries. Adv. Mater. 32, 2002976.
Crossref Google Scholar
[19]

Liu, H. Q., He, Y. N., Zhang, H., Cao, K. Z., Wang, S. D., Jiang, Y., Jing, Q. S., Jiao, L. F. (2021). Lowering the voltage-hysteresis of CuS anode for Li-ion batteries via constructing heterostructure. Chem. Eng. J. 425, 130548.
Crossref Google Scholar
[20]

Zhang, Z., Huang, Y., Liu, X. D., Chen, C., Xu, Z. P., Liu, P. B. (2020). Zeolitic imidazolate frameworks derived ZnS/Co3S4 composite nanoparticles doping on polyhedral carbon framework for efficient lithium/sodium storage anode materials. Carbon 157, 244–254.
Crossref Google Scholar
[21]

Hu, Y., Zhang, L. F., Bai, J. X., Liu, F. H., Wang, Z., Wu, W. P., Bradley, R., Li, L., Ruan, H., Guo, S. W. (2021). Boosting high-rate sodium storage of CuS via a hollow spherical nanostructure and surface pseudocapacitive behavior. ACS Appl. Energy Mater. 4, 8901–8909.
Crossref Google Scholar
[22]

Zeng, L. C., Pan, F. S., Li, W. H., Jiang, Y., Zhong, X. W., Yu, Y. (2014). Free-standing porous carbon nanofibers–sulfur composite for flexible Li–S battery cathode. Nanoscale 6, 9579–9587.
Crossref Google Scholar
[23]

Wang, Y., Wen, Z., Wang, C. C., Yang, C. C., Jiang, Q. (2021). MOF-derived Fe7S8 nanoparticles/N-doped carbon nanofibers as an ultra-stable anode for sodium-ion batteries. Small 17, 2102349.
Crossref Google Scholar
[24]

Xie, L. J., Tang, C., Bi, Z. H., Song, M. X., Fan, Y. F., Yan, C., Li, X. M., Su, F. Y., Zhang, Q., Chen, C. M. (2021). Hard carbon anodes for next-generation li-ion batteries: review and perspective. Adv. Energy Mater. 11, 2101650.
Crossref Google Scholar
[25]

Zhang, M., Shoaib, M., Fei, H. L., Wang, T., Zhong, J., Fan, L., Wang, L., Luo, H. Y., Tan, S., Wang, Y. Y., et al. (2019). Hierarchically porous N-doped carbon fibers as a free-standing anode for high-capacity potassium-based dual-ion battery. Adv. Energy Mater. 9, 1901663.
Crossref Google Scholar
[26]

Wu, Y. Q., Yang, H. X., Yang, Y., Pu, H., Meng, W. J., Gao, R. Z., Zhao, D. L. (2019). SnS2/Co3S4 hollow nanocubes anchored on S-doped graphene for ultrafast and stable Na-ion storage. Small 15, 1903873.
Crossref Google Scholar
[27]

Rao, Y., Zhu, K. J., Liang, P. H., Zhang, J., Zheng, H. J., Wang, J., Liu, J. S., Yan, K., Bao, N. Z. (2022). Synthesis of heterostructured dual metal sulfides by a high-temperature mixing hydrothermal method as an ultra-high rate anode for Li-ion batteries. CrystEngComm 24, 4698–4704.
Crossref Google Scholar
[28]

Yu, Q., Dong, T., Qiu, R. Y., Wang, H. W. (2021). Sulfur and nitrogen dual-doped carbon nanofiber with enlarged interlayer distance as a superior anode material for sodium-ion capacitors. Mater. Res. Bull. 138, 111211.
Crossref Google Scholar
[29]

Xu, D. F., Chen, C. J., Xie, J., Zhang, B., Miao, L., Cai, J., Huang, Y. H., Zhang, L. (2016). A Hierarchical N/S-codoped carbon anode fabricated facilely from cellulose/polyaniline microspheres for high-performance sodium-ion batteries. Adv. Energy Mater. 6, 1501929.
Crossref Google Scholar
[30]

Chen, M., Wang, W., Liang, X., Gong, S., Liu, J., Wang, Q., Guo, S. J., Yang, H. (2018). Sulfur/oxygen codoped porous hard carbon microspheres for high-performance potassium-ion batteries. Adv. Energy Mater. 8, 1800171.
Crossref Google Scholar
[31]

Kim, J. H., Ko, Y. I., Kim, Y. A., Kim, K. S., Yang, C. M. (2021). Sulfur-doped carbon nanotubes as a conducting agent in supercapacitor electrodes. J. Alloys Compd. 855, 157282.
Crossref Google Scholar
[32]

Cao, D. W., Kang, W. P., Wang, W. H., Sun, K. A., Wang, Y. Y., Ma, P., Sun, D. F. (2020). Okra-like Fe7S8/C@ZnS/N-C@C with core–double-shelled structures as robust and high-rate sodium anode. Small 16, 1907641.
Crossref Google Scholar
[33]

Zhang, W. L., Huang, Z. Y., Zhou, H. H., Li, S. L., Wang, C. Q., Li, H. X., Yan, Z. H., Wang, F., Kuang, Y. F. (2020). Facile synthesis of ZnS nanoparticles decorated on defective CNTs with excellent performances for lithium-ion batteries anode material. J. Alloys Compd. 816, 152633.
Crossref Google Scholar
[34]

Nam, J. S., Lee, J. H., Hwang, S. M., Kim, Y. J. (2019). New insights into the phase evolution in CuS during lithiation and delithiation processes. J. Mater. Chem. A 7, 11699–11708.
Crossref Google Scholar
[35]

Gan, Y. P., Xu, F. Q., Luo, J. M., Yuan, H. D., Jin, C. B., Zhang, L. Y., Fang, C., Sheng, O. W., Huang, H., Xia, Y., et al. (2016). One-pot biotemplate synthesis of FeS2 decorated sulfur-doped carbon fiber as high capacity anode for lithium-ion batteries. Electrochim. Acta 209, 201–209.
Crossref Google Scholar
[36]

Pathak, D. D., Dutta, D. P., Ravuri, B. R., Ballal, A., Joshi, A. C., Tyagi, A. K. (2021). An insight into the effect of g-C3N4 support on the enhanced performance of ZnS nanoparticles as anode material for lithium-ion and sodium-ion batteries. Electrochim. Acta 370, 137715.
Crossref Google Scholar
[37]

Zhang, J. C., Ni, S. B., Ma, J. J., Yang, X. L., Zhang, L. L. (2016). High capacity and superlong cycle life of Li3VO4/N–C hybrids as anode for high performance Li-ion batteries. J. Power Sources 301, 41–46.
Crossref Google Scholar
[38]

Xu, X. X., Li, L. J., Chen, H. Q., Guo, X. S., Zhang, Z H., Liu, J., Mao, C. M., Li, G. C. (2020). Constructing heterostructured FeS2/CuS nanospheres as high rate performance lithium ion battery anodes. Inorg. Chem. Front. 7, 1900–1908.
Crossref Google Scholar
[39]

Cao, L., Gao, X. W., Zhang, B., Ou, X., Zhang, J. F., Luo, W. B. (2020). Bimetallic sulfide Sb2S3@FeS2 hollow nanorods as high-performance anode materials for sodium-ion batteries. ACS Nano 14, 3610–3620.
Crossref Google Scholar
[40]

Ren, J. H., Wang, Z. Y., Xu, P., Wang, C., Gao, F., Zhao, D. C., Liu, S. P., Yang, H., Wang, D., Niu, C. M., et al. (2022). Porous Co2VO4 nanodisk as a high-energy and fast-charging anode for lithium-ion batteries. Nano-Micro Lett. 14, 5.
Crossref Google Scholar
[41]

Li, Q., Li, H. S., Xia, Q. T., Hu, Z. Q., Zhu, Y., Yan, S. S., Ge, C., Zhang, Q. H., Wang, X. X., Shang, X. T., et al. (2021). Extra storage capacity in transition metal oxide lithium-ion batteries revealed by in situ magnetometry. Nat. Mater. 20, 76–83.
Crossref Google Scholar
[42]

Zhang, J. J., Cao, D. W., Wu, Y., Cheng, X. L., Kang, W. P., Xu, J. (2020). Phase transformation and sulfur vacancy modulation of 2D layered tin sulfide nanoplates as highly durable anodes for pseudocapacitive lithium storage. Chem. Eng. J. 392, 123722.
Crossref Google Scholar
[43]

Cao, L., Zhang, B., Ou, X., Wang, C. H., Peng, C. L., Zhang, J. F. (2019). Synergistical coupling interconnected ZnS/SnS2 nanoboxes with polypyrrole-derived N/S dual-doped carbon for boosting high-performance sodium storage. Small 15, 1804861.
Crossref Google Scholar
[44]

Fang, Y. J., Guan, B. Y., Luan, D. Y., Lou, X. W. (2019). Synthesis of CuS@CoS2 double-shelled nanoboxes with enhanced sodium storage properties. Angew. Chem., Int. Ed. 58, 7739–7743.
Crossref Google Scholar
[45]

Zhao, N., Wang, C., Li, B. H., Shen, W. C., Kang, F. Y., Huang, Z. H. (2022). Construction of flexible lignin/polyacrylonitrile-based carbon nanofibers for dual-carbon sodium-ion capacitors. J. Mater. Sci. 57, 11809–11823.
Crossref Google Scholar
[46]

Ren, X. L., Ai, D. S., Zhan, C. Z., Lv, R. T., Kang, F. Y., Huang, Z. H. (2020). 3D porous Li3VO4@C composite anodes with ultra-high rate capacity for lithium-ion capacitors. Electrochim. Acta 355, 136819.
Crossref Google Scholar
[47]

Wang, R. H., Zhao, Q. N., Zheng, W. K., Ren, Z. L., Hu, X. L., Li, J., Lu, L., Hu, N., Molenda, J., Liu, X. J., et al. (2019). Achieving high energy density in a 4.5 V all nitrogen-doped graphene based lithium-ion capacitor. J. Mater. Chem. A 7, 19909–19921.
Crossref Google Scholar
[48]

Sivakkumar, S. R., Nerkar, J. Y., Pandolfo, A. G. (2010). Rate capability of graphite materials as negative electrodes in lithium-ion capacitors. Electrochim. Acta 55, 3330–3335.
Crossref Google Scholar
[49]

Dong, S. Y., Li, H. S., Wang, J. J., Zhang, X. G., Ji, X. L. (2017). Improved flexible Li-ion hybrid capacitors: techniques for superior stability. Nano Res. 10, 4448–4456.
Crossref Google Scholar
[50]

Liu, C., Khosrozadeh, A., Ren, Q. Q., Yan, L. H., Goh, K., Li, S. H., Liu, J., Zhao, L., Gu, D. M., Wang, Z. B. (2021). Intercalation-pseudocapacitance hybrid anode for high rate and energy lithium-ion capacitors. J. Energy Chem. 55, 459–467.
Crossref Google Scholar
[51]

Tao, S. S., Momen, R., Luo, Z., Zhu, Y. R., Xiao, X. H., Cao, Z. W., Xiong, D. Y., Deng, W. T., Liu, Y. C., Hou, H. S. et al. (2023). Trapping lithium selenides with evolving heterogeneous interfaces for high-power lithium-ion capacitors. Small 19, 2207975.
Crossref Google Scholar
[52]

Wang, Y. K., Liu, M. C., Cao, J. Y., Zhang, H. J., Kong, L. B., Trudgeon, D. P., Li, X. H., Walsh, F. C. (2020). 3D hierarchically structured CoS nanosheets: Li+ storage mechanism and application of the high-performance lithium-ion capacitors. ACS Appl. Mater. Interfaces 12, 3709–3718.
Crossref Google Scholar
[53]

Zhou, H. Y., Lin, L. W., Sui, Z. Y., Wang, H. Y., Han, B. H. (2023). Holey Ti3C2 MXene-derived anode enables boosted kinetics in lithium-ion capacitors. ACS Appl. Mater. Interfaces 15, 12161–12170.
Crossref Google Scholar
[54]

Ma, Y. B., Wang, K., Xu, Y. N., Zhang, X. D., Peng, Q. F., Li, S. N., Zhang, X., Sun, X. Z., Ma, Y. W. (2023). Dehalogenation produces graphene wrapped carbon cages as fast-kinetics and large-capacity anode for lithium-ion capacitors. Carbon 202, 175–185.
Crossref Google Scholar
[55]

Liu, W. J., An, Y. B, Wang, L., Hu, T., Li, C., Xu, Y. N., Wang, K., Sun, X. Z., Zhang, H. T., Zhang, X. et al. (2023). Mechanically flexible reduced graphene oxide/carbon composite films for high-performance quasi-solid-state lithium-ion capacitors. J. Energy Chem. 80, 68–76.
Crossref Google Scholar
[56]

Lei, D., Hou, Z. D., Li, N., Cao, Y. J., Ren, L. B., Liu, H. Y., Zhang, Y., Wang, J. G. (2023). A homologous N/P-codoped carbon strategy to streamline nanostructured MnO/C and carbon toward boosted lithium-ion capacitors. Carbon 201, 260–268.
Crossref Google Scholar
Energy Materials and Devices
Volume 1 Issue 2,
December 2023
Article number: 9370012
DOI: 10.26599/EMD.2023.9370012
Cite this article:
Li B, Wang C, Qin Z, et al. ZnS/CuS nanoparticles encapsulated in multichannel carbon fibers as high-performance anode materials for flexible Li-ion capacitors. Energy Materials and Devices, 2023, 1(2): 9370012. https://doi.org/10.26599/EMD.2023.9370012

2933

Views

473

Downloads

9

Crossref

Altmetrics
Received: 15 October 2023
Revised: 27 November 2023
Accepted: 01 December 2023
Published: 13 December 2023
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Return