AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
PDF (1.6 MB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Laser spot associated high-saturation phosphor-in-glass film for transmissive and reflective high-brightness laser lighting

Zikang YuaJiuzhou ZhaoaQing WangbYun MoucMingxiang ChenbYang Penga( )
School of Aerospace Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
School of Integrated Circuits, Sun Yat-sen University, Shenzhen 518107, China
Show Author Information

Graphical Abstract

Abstract

Phosphor-in-glass (PiG) film is a promising luminescent material in high-brightness laser lighting for its advantages of high efficiency, outstanding color quality, and low-cost preparation, which must bear high laser power (LP) and laser power density (LPD) simultaneously to enable high-luminance light. Herein, laser spot associated high-saturation PiG film was proposed for transmissive and reflective high-brightness laser lighting. Two types of PiG films were prepared by printing and sintering La3Si6N11:Ce3+ (LSN) phosphor-borosilicate glass pastes on a sapphire substrate (PiG-S) and an AlN substrate (PiG-A), respectively. The PiG films with perfect crystal structure of phosphor were reliably bonded on the substrates. The effects of laser spot areas on the luminescence saturation of LP and LPD were investigated in the PiG films. With the increase of laser spot area from 0.5 to 2.5 mm2, the LP threshold of PiG films is gradually raised, while the LPD threshold of PiG films is decreased. The PiG-S withstands a high LP of 23.46 W and a high LPD of 20.64 W/mm2, enabling white light with a luminous flux of 3677 lm. The PiG-A withstands a high LP of 41.12 W and a high LPD of 35.56 W/mm2, enabling white light with a luminous flux of 2882 lm. Moreover, the PiG-A maintains lower working temperature compared with the PiG-S, and the temperatures reduce with the increasing laser spot area. The results demonstrate that the laser spot associated PiG films realize high saturation thresholds of LP and LPD simultaneously, and enable high luminance for laser lighting.

Electronic Supplementary Material

Download File(s)
JAC0790_ESM.pdf (2.2 MB)

References

[1]
Tsao JY, Crawford MH, Coltrin ME, et al. Toward smart and ultra-efficient solid-state lighting. Adv Opt Mater 2014, 2: 809836.
[2]
Li SX, Wang L, Hirosaki N, et al. Color conversion materials for high-brightness laser-driven solid-state lighting. Laser Photonics Rev 2018, 12: 1800173.
[3]
Yang CC, Zhang XY, Kang J, et al. Recent progress on garnet phosphor ceramics for high power solid-state lighting. J Mater Sci Technol 2023, 166: 120.
[4]
Zhou TY, Hou C, Zhang L, et al. Efficient spectral regulation in Ce:Lu3(Al, Cr)5O12 and Ce:Lu3(Al, Cr)5O12/Ce: Y3Al5O12 transparent ceramics with high color rendering index for high-power white LEDs/LDs. J Adv Ceram 2021, 10: 11071118.
[5]
Wierer JJ Jr, Tsao JY, Sizov DS. Comparison between blue lasers and light-emitting diodes for future solid-state lighting. Laser Photonics Rev 2013, 7: 963993.
[6]
Ma YP, Luo XB. Packaging for laser-based white lighting: Status and perspectives. J Electron Packag 2020, 142: 010801.
[7]
Mou Y, Yu ZK, Lei ZY, et al. Enhancing opto-thermal performances of white laser lighting by high reflective phosphor converter. J Alloys Compd 2022, 918: 165637.
[8]
Li SX, Guo YQ, Xie RJ. Laser phosphors for next-generation lighting applications. Acc Mater Res 2022, 3: 12991308.
[9]
Bao SY, Liang YY, Wang LS, et al. Superhigh-luminance Ce:YAG phosphor in glass and phosphor-in-glass film for laser lighting. ACS Sustainable Chem Eng 2022, 10: 81058114.
[10]
Sui P, Lin H, Lin Y, et al. Toward high-power-density laser-driven lighting: Enhancing heat dissipation in phosphor-in-glass film by introducing h-BN. Opt Lett 2022, 47: 34553458.
[11]
Ding XR, Chen MQ, Yan CM, et al. Enhancing thermal stability of laser-driven phosphor converter by utilizing copper powder sintering framework/paraffin. IEEE Trans Electron Devices 2022, 69: 582589.
[12]
Yan CM, Ding XR, Chen MQ, et al. Research on laser illumination based on phosphor in metal (PiM) by utilizing the boron nitride-coated copper foams. ACS Appl Mater Interfaces 2021, 13: 2999630007.
[13]
Wang LH, Liu JW, Xu L, et al. Realizing high-power laser lighting: Artfully importing micrometer BN into Ce:GdYAG phosphor-in-glass film. Laser Photonics Rev 2023, 17: 2200585.
[14]
Peng Y, Mou Y, Sun QL, et al. Facile fabrication of heat-conducting phosphor-in-glass with dual-sapphire plates for laser-driven white lighting. J Alloys Compd 2019, 790: 744749.
[15]
Zhou JB, Wang YF, Chen YY, et al. Single-crystal red phosphors and their core–shell structure for improved water-resistance for laser diodes applications. Angew Chem 2021, 133: 39863991.
[16]
Wang ZL, Yang ZY, Wang N, et al. Single-crystal red phosphors: Enhanced optical efficiency and improved chemical stability for wLEDs. Adv Optical Mater 2020, 8: 1901512.
[17]
Lin SS, Lin H, Huang QM, et al. Highly crystalline Y3Al5O12:Ce3+ phosphor-in-glass film: A new composite color converter for next-generation high-brightness laser-driven lightings. Laser Photonics Rev 2022, 16: 2200523.
[18]
Cheng ZQ, Liu X, Chen XR, et al. Composition and luminescence properties of highly robust green-emitting LuAG:Ce/Al2O3 composite phosphor ceramics for high-power solid-state lighting. J Adv Ceram 2023, 12: 625633.
[19]
Liu X, Qian XL, Zheng P, et al. Composition and structure design of three-layered composite phosphors for high color rendering chip-on-board light-emitting diode devices. J Adv Ceram 2021, 10: 729740.
[20]
Xu J, Jiang Z, Gu W, et al. Design of a β-SiAlON:Eu based phosphor-in-glass film with high saturation threshold for high-luminance laser-driven backlighting. Appl Phys Lett 2021, 119: 231102.
[21]
Xu L, Wang LH, Bao SY, et al. High-efficiency yellow-emitting La3Si6N11:Ce phosphor-in-glass for laser-driven white lighting. Ceram Int 2022, 48: 2395523962.
[22]
Huang QG, Sui P, Huang F, et al. Toward high-quality laser-driven lightings: Chromaticity-tunable phosphor-in-glass film with “phosphor pattern” design. Laser Photonics Rev 2022, 16: 2200040.
[23]
Lin T, Chen HX, Li SX, et al. Bi-color phosphor-in-glass films achieve superior color quality laser-driven stage spotlights. Chem Eng J 2022, 444: 136591.
[24]
Yao Q, Hu P, Sun P, et al. YAG:Ce 3+ transparent ceramic phosphors brighten the next-generation laser-driven lighting. Adv Mater 2020, 32: 1907888.
[25]
Liang YY, Bao SY, Zhang YJ, et al. A unique green-emitting phosphor-in-glass (PiG) for solid state laser lighting and displays. J Mater Chem C 2021, 9: 1275112758.
[26]
Wei R, Wang L, Zheng P, et al. On the luminance saturation of phosphor-in-glass (PiG) films for blue-laser-driven white lighting: Effects of the phosphor content and the film thickness. J Eur Ceram Soc 2019, 39: 19091917.
[27]
Lenef A, Kelso JF, Serre J, et al. Co-sintered ceramic converter for transmissive laser-activated remote phosphor conversion. Appl Phys Lett 2022, 120: 021104.
[28]
Li Q, Xiao WG, Zhang D, et al. Phosphor-in-silica-glass: Filling the gap between low- and high-brightness solid-state lightings. Laser Photonics Rev 2022, 16: 2200553.
[29]
Huang QG, Lin H, Wang B, et al. Patterned glass ceramic design for high-brightness high-color-quality laser-driven lightings. J Adv Ceram 2022, 11: 862873.
[30]
Liang YY, Bao SY, Wang Y, et al. Highly thermally stable red phosphor-in-glass films for high-power laser lighting. J Lumin 2022, 248: 118930.
[31]
Wang L, Wei R, Zheng P, et al. Realizing high-brightness and ultra-wide-color-gamut laser-driven backlighting by using laminated phosphor-in-glass (PiG) films. J Mater Chem C 2020, 8: 17461754.
[32]
Meng Y, Zhu QQ, Huang MH, et al. Sandwich structured phosphor-in-glass films enabling laser lighting with superior optical properties. Ceram Int 2022, 48: 1362613633.
[33]
Hong MD, Chen C, Wang HP, et al. Improved optical properties of phosphors-in-glass through the optimal size distribution of glass powder. Dalton Trans 2023, 52: 72717278.
[34]
Zheng P, Li SX, Wang L, et al. Unique color converter architecture enabling phosphor-in-glass (PiG) films suitable for high-power and high-luminance laser-driven white lighting. ACS Appl Mater Interfaces 2018, 10: 1493014940.
[35]
Jin L, Liu ST, Si SC, et al. Targeting cooling for YAG: Ce3+-based laser-driven lighting device by blending high thermal conductivity AlN in phosphor-sapphire composite. Ceram Int 2022, 48: 3476034768.
[36]
Peng Y, Yu ZK, Zhao JZ, et al. Unique sandwich design of high-efficiency heat-conducting phosphor-in-glass film for high-quality laser-driven white lighting. J Adv Ceram 2022, 11: 18891900.
[37]
Peng Y, Liu JX, Mou Y, et al. Heat dissipation enhancement of phosphor-converted white laser diodes by thermally self-managing phosphor-in-glass. IEEE Trans Electron Devices 2020, 67: 42884292.
[38]
Liu ZH, Hu P, Jiang HJ, et al. CaAlSiN3:Eu2+/Lu3Al5O12:Ce3+ phosphor-in-glass film with high luminous efficiency and CRI for laser diode lighting. J Mater Chem C 2021, 9: 35223530.
[39]
Mou Y, Zhao JZ, Yu ZK, et al. Highly reflective interface design for phosphor-in-glass converter enabling ultrahigh efficiency laser-driven white lighting. J Eur Ceram Soc 2022, 42: 75797586.
[40]
Yu ZK, Zhao JZ, Liu JX, et al. Heat-conducting LSN:Ce-in-glass film on AlN substrate for high-brightness laser-driven white lighting. Ceram Int 2022, 48: 3653136538.
[41]
Hei LL, Li SX, Cheng X, et al. Effect of laser spot regulation on evaluation of laser phosphors. Chin J Lumin 2021, 42: 16461652.
[42]
Xu J, Wang LJ, Gu W, et al. Emitting area limitation via scattering control in phosphor film realizing high-luminance laser lighting. J Eur Ceram Soc 2022, 42: 608615.
[43]
You SH, Li SX, Zheng P, et al. A thermally robust La3Si6N11:Ce-in-glass film for high-brightness blue-laser-driven solid state lighting. Laser Photonics Rev 2019, 13: 1800216.
[44]
Xu L, Wang XD, Wang LH, et al. Design of a novel La3Si6N11:Ce3+ phosphor-in-glass film for high power laser lighting: Luminous efficiency toward 200 lm·W–1. ACS Sustainable Chem Eng 2022, 10: 1281712825.
[45]
Huang MH, Zhu QQ, Li SX, et al. Thermally robust Al2O3–La3Si6N11:Ce3+ composite phosphor-in-glass (PiG) films for high-power and high-brightness laser-driven lighting. J Mater Chem C 2023, 11: 488496.
[46]
Zhu QQ, Li SX, Yuan Q, et al. Transparent YAG:Ce ceramic with designed low light scattering for high-power blue LED and LD applications. J Eur Ceram Soc 2021, 41: 735740.
[47]
Zhao JZ, Mou Y, Yu ZK, et al. Microstructured interface modification of laser-driven phosphor-in-glass-film for ultra-high-efficiency white lighting. J Alloys Compd 2023, 960: 170744.
[48]
Mou Y, Wang Q, Guo ZY, et al. Nitride phosphor-in-glass films enabling high-performance white light in transmissive and reflective laser lighting. Ceram Int 2023, 49: 1182111828.
[49]
Peng Y, Zhao JZ, Yu ZK, et al. High-performance phosphor-in-glass film on thermoelectric generator for non-radiative energy recycling in laser lighting. Adv Mater Technol 2023, 8: 2202162.
[50]
Wang Y, Xu L, Wang LH, et al. High power multicolor composite fluorescent glass coated with graphene monolayer for laser lighting. J Alloys Compd 2023, 941: 168986.
[51]
Xie B, Wang YJ, Liu HC, et al. Targeting cooling for quantum dots by 57.3 ℃ with air-bubbles-assembled three-dimensional hexagonal boron nitride heat dissipation networks. Chem Eng J 2022, 427: 130958.
Journal of Advanced Ceramics
Pages 1821-1832
Cite this article:
Yu Z, Zhao J, Wang Q, et al. Laser spot associated high-saturation phosphor-in-glass film for transmissive and reflective high-brightness laser lighting. Journal of Advanced Ceramics, 2023, 12(9): 1821-1832. https://doi.org/10.26599/JAC.2023.9220790

1855

Views

319

Downloads

30

Crossref

28

Web of Science

30

Scopus

2

CSCD

Altmetrics

Received: 20 June 2023
Revised: 17 July 2023
Accepted: 23 July 2023
Published: 18 September 2023
© The Author(s) 2023.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Return