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Research Article | Open Access

A Voltammetric Properties of Biopolymer Nano-Composites Based Polybutylene Succinate/Epoxidized Palm Oil

Manar Ghyath Abd-Almutalib Al-Mosawy1, Emad Abbas Jaffar Al-Mulla2( ), Muhammed Mizher Radhi3
Department of Chemistry, Faculty of Science, University of Kufa, P.O. Box 21, An-Najaf 54001, Iraq
College of Health and Medical Techniques, Al-Furat Al-Awsat Technical University, 54003 Al-Kufa, Iraq
Radiologic Technical Department, Health and Medical Technology College-Baghdad, Middle Technical University, Baghdad, Iraq
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Abstract

A glassy carbon electrode (GCE) was modified with a polybutylene succinate/epoxidized palm oil (PBS/EPO) clay nanocomposites; by using solution evaporation method, a new modified electrode PBS/EPO-clay nanocomposite was produced. The redox process of K4[Fe(CN)6] during cyclic voltammetry was studied using the PBS/EPO-clay nanocomposites. It was found that the peak separation (ΔEpa-c) between the redox peaks of Fe(Ⅱ)/Fe(Ⅲ) in an aqueous solution of 0.1 M KClO4 and the current ratio of redox current peaks, (Ipa/Ipc) was ≈ 1 for the modified working electrode with PBS/EPO-clay nanocomposites, indicating good reversibility with weak conductivity of the modified electrode. The physical properties of the modified electrode PBS/EPO-clay nanocomposites included good hardness, high adhesion to the glassy carbon surfaces of electrode collectors, solubility and good stability of the PBS/EPO-clay nanocomposites at different pH media. Also, the sensitivity of the electrochemical analysis by cyclic voltammetric method was significantly dependent on the pH and the scan rate (SR). It was found that the couple of redox current peaks of K4[Fe(CN)6] in KClO4 solution were a reversible process: Fe(Ⅲ)/Fe(Ⅱ).

Keywords

Cyclic voltammetryPBS/EPO-clay nanocompositesKClO4Fe(Ⅱ)/Fe(Ⅲ)K4[Fe(CN)6]

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Nano Biomedicine and Engineering
Volume 10 Issue 3,
September 2018
Pages 217-223
DOI: 10.5101/nbe.v10i3.p217-223
Cite this article:
Ghyath Abd-Almutalib Al-Mosawy M, Abbas Jaffar Al-Mulla E, Mizher Radhi M. A Voltammetric Properties of Biopolymer Nano-Composites Based Polybutylene Succinate/Epoxidized Palm Oil. Nano Biomedicine and Engineering, 2018, 10(3): 217-223. https://doi.org/10.5101/nbe.v10i3.p217-223

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Received: 16 March 2018
Accepted: 18 April 2018
Published: 23 July 2018
© Manar Ghyath Abd-Almutalib Al-Mosawy, Emad Abbas Jaffar Al-Mulla, and Muhammed Mizher Radhi.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
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