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Research Article | Open Access

A Voltammetric Properties of Biopolymer Nano-Composites Based Polybutylene Succinate/Epoxidized Palm Oil

Manar Ghyath Abd-Almutalib Al-Mosawy1, Emad Abbas Jaffar Al-Mulla2( ), Muhammed Mizher Radhi3
Department of Chemistry, Faculty of Science, University of Kufa, P.O. Box 21, An-Najaf 54001, Iraq
College of Health and Medical Techniques, Al-Furat Al-Awsat Technical University, 54003 Al-Kufa, Iraq
Radiologic Technical Department, Health and Medical Technology College-Baghdad, Middle Technical University, Baghdad, Iraq
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Abstract

A glassy carbon electrode (GCE) was modified with a polybutylene succinate/epoxidized palm oil (PBS/EPO) clay nanocomposites; by using solution evaporation method, a new modified electrode PBS/EPO-clay nanocomposite was produced. The redox process of K4[Fe(CN)6] during cyclic voltammetry was studied using the PBS/EPO-clay nanocomposites. It was found that the peak separation (ΔEpa-c) between the redox peaks of Fe(Ⅱ)/Fe(Ⅲ) in an aqueous solution of 0.1 M KClO4 and the current ratio of redox current peaks, (Ipa/Ipc) was ≈ 1 for the modified working electrode with PBS/EPO-clay nanocomposites, indicating good reversibility with weak conductivity of the modified electrode. The physical properties of the modified electrode PBS/EPO-clay nanocomposites included good hardness, high adhesion to the glassy carbon surfaces of electrode collectors, solubility and good stability of the PBS/EPO-clay nanocomposites at different pH media. Also, the sensitivity of the electrochemical analysis by cyclic voltammetric method was significantly dependent on the pH and the scan rate (SR). It was found that the couple of redox current peaks of K4[Fe(CN)6] in KClO4 solution were a reversible process: Fe(Ⅲ)/Fe(Ⅱ).

Keywords

Cyclic voltammetryPBS/EPO-clay nanocompositesKClO4Fe(Ⅱ)/Fe(Ⅲ)K4[Fe(CN)6]

References

[1]

M.M. Radhi, W.T. Tan, and M.Z. Rahman, Electrochemical characterization of the redox couple of[Fe(CN)6]-3Fe(CN)6]-4 mediated by a grafted polymer modified glassy carbon electrode. Journal of Chemical Engineering of Japan, 2010, 43: 927-931.
Crossref Google Scholar
[2]

D.E. Labaye, C. Jerome, V.M. Gueskin, et al., Full electrochemical synthesis of conducting polymer films chemically grafted to conducting surfaces. J. Am. Chem. Soc., 2002, 18: 5222-5230.
Crossref Google Scholar
[3]

M.L. Peter, G.H. Rob, and M.A. Hempenius, Electrochemistry of surface-grafted stimulus-responsive monolayers of poly(ferrocenyldimethylsilane) on gold. Langmuir, 2005, 21: 5115-5123.
Crossref Google Scholar
[4]

C.J. Chuy, E. Ding, S. Swanson, et al., Conductivity and electrochemical ORR mass transport properties of solid polymer electrolytes containing poly(styrene sulfonic acid) graft chains. J. Electrochem. Soc., 2003, 150: 271-279.
Crossref Google Scholar
[5]

M.M. Radhi, W.T. Tan, and A.J. Haider, Electrochemical characterization of the redox couple of Fe(Ⅱ)/Fe(Ⅲ) mediated by a grafted polymer electrode in nonaqueous electrolyte. Int. J. Electrochem. Sci., 2012, 7: 121-140.
Google Scholar
[6]

H. Xiong W. Zi-Dong, and D. Xie, Stable polymer electrolytes based on polyether-grafted ZnO nanoparticles for all-solid-state lithium batteries. J. Mater. Chem., 2006, 16: 1345-1349.
Crossref Google Scholar
[7]

A. Oishi, M. Zhang, K. Nakayama, et al., Synthesis of poly(butylene succinate) and poly(ethylene succinate) including diglycollate moiety. Polym. J., 2006, 38(7): 710-715.
Crossref Google Scholar
[8]

E.A.J. Al-Mulla, Preparation of polylactic acid/epoxidized palm oil/fatty nitrogen compounds modified clay nanocomposites by melt blending. Polym. Scie. Ser. A, 2001, 53(2): 149-157.
Crossref Google Scholar
[9]

M.M. Reddy, A.K. Mohanty, and M. Misra, Biodegradable blends from plasticized soy meal, polycaprolactone, and poly(butylene succinate). Mac. Mol. Mat. Eng., 2011, 297: 455-463.
Crossref Google Scholar
[10]

H.S. Cho, H.S. Moon, and M. Kim, Biodegradability and biodegradation rate of poly(caprolactone)-starch blend and poly(butylene succinate) biodegradable polymer under aerobic and anaerobic environment. Was. Manag., 2010, 31: 475-480.
Crossref Google Scholar
[11]

S. Sugihara, K. Toshima, and S. Matsumura, New strategy for enzymatic synthesis of high-molecular-weight poly(butylene succinate) via cyclic oligomers. Mac. Molec. Rap. Comm., 2006, 7: 203-207.
Crossref Google Scholar
[12]

L.L. Yu, J. Cheng, and W.L. Qu, Mechanical properties of poly(butylene succinate) (PBS) biocomposites reinforced with surface modified jute fibre. Composites Part A: Appl. Sci. and Manuf., 2009, 40: 669-674.
Crossref Google Scholar
[13]

E.A.J. Al-Mulla, W.M.Z.W. Yunus, and N.A.B. Ibrahim, Epoxidized palm oil plasticized polylactic acid/fatty nitrogen compound modified clay nanocomposites: Preparation and characterization. Polym. Polym. Compo., 2010, 18: 451-459.
Crossref Google Scholar
[14]

K. Dean, L. Yu, S. Bateman, et al., Gelatinized starch/biodegradable polyester blends: Processing, morphology, and properties. J. of App. Polym. Scie., 2007, 103(2): 802-811.
Crossref Google Scholar
[15]

E.A.J. Al-Mulla, W.M.Z.W. Yunus, and N.A.B. Ibrahim, Properties of epoxidized palm oil plasticized polylactic acid, J. Mat. Sci., 2010, 45: 1942-1946.
Crossref Google Scholar
[16]

E.A.J. Al-Mulla, Preparation of new polymer nanocomposites based on poly (lactic acid)/fatty nitrogen compounds modified clay by a solution casting process. Fib. and Polym., 2011, 12(4): 444-450.
Crossref Google Scholar
[17]

E.A.J. Al-Mulla, Polylactic acid/epoxidized palm oil/fatty nitrogen compounds modified clay nanocomposites: preparation and characterization. Kor. J. of Chem. Eng., 2011, 28(2): 620-626.
Crossref Google Scholar
[18]

M.M. Radhi, E.A.J. Al-Mulla, Use of a grafted polymer electrode to study mercury ions by cyclic voltammetry. Res. on Chem. Interm., 2015, 41: 1413-1420.
Crossref Google Scholar
[19]

F.A. Shemmari, A.A.A. Rabah, Comparative study of different surfactants for natural rubber clay nanocomposite preparation. Rendiconti Lincei, 2014, 25: 409-413.
Crossref Google Scholar
[20]

J.W. Park, S.S. Im, Phase behavior and morphology in blends of poly(L-lactic acid) and poly(butylene succinate). J. Appl. Polym. Sci., 2002, 86: 647-655.
Crossref Google Scholar
[21]

T. Yokohara, M. Yamaguchi, Structure and properties for biomassbased polyester blends of PLA and PBS. Eur. Polym. J., 2008, 44: 677-685.
Crossref Google Scholar
[22]

D.J. Kim, W.S. Kim, and D.H. Lee, Modification of poly(butylene succinate) with peroxide: crosslinking, physical and thermal properties, and biodegradation. J. Appl. Polym. Sci., 2001, 81: 1115-1124.
Crossref Google Scholar
[23]

E.A.J. Al-Mulla, Lipase-catalyzed synthesis of fatty thioic acids from palm oil. J. Ole. Sci., 2011, 60(1): 41-45.
Crossref Google Scholar
[24]

E.A. J. Al-Mulla, W. M.Z.W. Yunus, N.A.B. Ibrahim, et al., Di fatty acyl urea from corn oil: Synthesis and characterization. J. Oleo Sci., 2010, 59: 157-160.
Crossref Google Scholar
[25]

Z. Kulinski, E. Piorkowska, Crystallization, structure and properties of plasticized poly(l-lactide). Polym., 2005, 46: 10290-10300.
Crossref Google Scholar
[26]

Z. Ren, L. Dong, and Y. Yang, Dynamic mechanical and thermal properties of plasticized poly(lactic acid). J. Appl. Polym. Sci., 2006, 101: 1583-1590.
Crossref Google Scholar
[27]

E.P. Giannelis, Polymer-layered silicate nanocomposites: synthesis, propertiesand applications. Appl. Organomet. Chem., 1998, 12: 675-680.
Crossref
[28]

B. Zidelkheir, M. Abdelgoad, Effect of surfactant agent upon the structure of montmorillonite. J. Therm. Anal. Calorim., 2008, 94: 181-187.
Crossref Google Scholar
[29]

E.P. Giannelis, R. Krishnamoorti, and E. Manias, Polymer-silicate nanocomposites model systems for confined polymers and polymer brushes. Adv. Polym. Sci., 1999, 138: 107-143.
Crossref Google Scholar
[30]

E.A.J. Al-Mulla, A.H. Suhail, and A.A. Saadon, New biopolymer nanocomposites based on epoxidized soybean oil plasticized poly(lactic acid)/fatty nitrogen compounds modified clay: Preparation andcharacterization. Ind. Crops Prod., 2011, 33: 23-29.
Crossref Google Scholar
Nano Biomedicine and Engineering
Volume 10 Issue 3,
September 2018
Pages 217-223
DOI: 10.5101/nbe.v10i3.p217-223
Cite this article:
Ghyath Abd-Almutalib Al-Mosawy M, Abbas Jaffar Al-Mulla E, Mizher Radhi M. A Voltammetric Properties of Biopolymer Nano-Composites Based Polybutylene Succinate/Epoxidized Palm Oil. Nano Biomedicine and Engineering, 2018, 10(3): 217-223. https://doi.org/10.5101/nbe.v10i3.p217-223

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Received: 16 March 2018
Accepted: 18 April 2018
Published: 23 July 2018
© Manar Ghyath Abd-Almutalib Al-Mosawy, Emad Abbas Jaffar Al-Mulla, and Muhammed Mizher Radhi.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
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