This study introduces a pioneering design concept termed the “dual-feedback healing mechanism”, which investigates the relationship between oxidation products and protective coatings. Specifically, it focuses on channeling oxidation products generated at exposed cracks in the substrate to interact with the antioxidant coatings, enabling a self-repair mechanism for cracks. BN_f/SiBN was chosen as the ceramic matrix, while the Si‒O‒Al system served as the antioxidant coating. The dynamic process of obtaining Si–O–Al (SOAC) coating involving the pyrolysis of organic precursors and the dual-feedback healing mechanism were systematically investigated. These findings indicate that when the temperature surpasses 1150 °C, the exposed BN fibers at the cracks are oxidized, transforming into B₂O₃(g). Subsequently, B₂O₃(g) reacts with SiO₂, forming a SiBO mixture. The mixture effectively diminishes the viscosity of the coating, enabling it to flow and form a fresh protective layer that effectively blocks O₂ infiltration. Consequently, after oxidation at 1500 °C, the coated samples experience a mere 3% weight loss. This technology emphasizes the interconnectivity during material transformation, utilizing matrix oxidation products as a driving force for self-healing of the coating. This approach achieves intelligent-like, targeted closure of oxygen pathways, thereby pioneering a novel concept and direction for the advancement of antioxidant coatings. Consequently, this approach not only enhances our understanding of the fundamental nature of “self-healing” but also holds significant potential in the development of reparable antioxidant coatings.

Wood-derived carbon has a 3D porous framework composed of through channels along the growth direction, which is a suitable matrix for preparing electromagnetic wave (EMW) absorbing materials with low cost, light weight, and environmental friendliness. Herein, the carbonized wood decorated by short cone-like NiCo₂O₄ (NiCo₂O₄@CW) with highly ordered straight-channel architecture was successfully manufactured through a facile calcination procedure. The horizontal arrangement of the through channels of NiCo₂O₄@CW (H-NiCo₂O₄@CW) exhibits a strong reflection loss value of -64.0 dB at 10.72 GHz with a thickness of 3.62 mm and a low filling ratio of 26 wt% (with the density of 0.98 g·cm^-3), and the effective absorption bandwidth (EAB) is 8.08 GHz (9.92-18.0 GHz) at the thickness of 3.2 mm. The excellent microwave absorption (MA) property was ascribed to the ordered-channel structure with abundant interfaces and defects from NiCo₂O₄@CW, which could promote the interfacial polarization and dipole polarization. What is more, this advantageous structure increased the multiple reflections and scattering. Finite element analysis (FEA) simulation is carried out to detect the interaction between the prepared material and EMW when the ordered channels are arranged in different directions. This research provides a low-cost, sustainable, and environmentally friendly strategy for using carbonized wood to fabricate microwave absorbers with strong attenuation capabilities and light weight.

Carbon fibers reinforced lithium aluminosilicate matrix composites (C_f/LAS) were prepared by slurry infiltration combined with a hot press procedure. The friction, wear behavior, and wear mechanisms of C_f/LAS composites under dry sliding conditions were investigated. The results show that the coefficient of friction (COF) initially increased with the increase in carbon fiber content, and reached the maximum value of 0.20 for the 33%C_f/LAS composite. The COF increased sharply with increasing sample temperature from RT to 300 °C. The COF remained stable in the temperature range of 300-500 °C. The two wear mechanisms of LAS glass- ceramics are fatigue wear and abrasive wear. The C_f/LAS composites demonstrate slight spalling and shallow scratches. These results show that carbon fibers improve the mechanical properties and wear resistance of C_f/LAS composites.