In the present study, Zn-doped CaTiO₃ nanocrystalline was synthesized to study the thermistor behavior with temperature. The X-ray powder diffraction analysis showed the formation of a single-phase orthorhombic structure at room temperature. The electrical resistance of the Zn-doped CaTiO₃ increased with increasing doping concentration and decreased at higher measuring temperature, showing a negative temperature coefficient of resistance (NTCR) behavior. Different thermistor parameters were calculated using Steinhart–Hart equations, whilst time domain analysis confirmed faster response towards applied voltage.