The construction of a thin stable shell to encapsulate perovskite with effective carrier transport is a promising strategy to fabricate highly efficient and stable perovskite based optoelectronic devices. However, it is generally difficult to control the thickness and location of the encapsulating materials, ideally on perovskite grains. In this work, we developed a one-step method for the growth of titanium alkoxide networks in-situ in perovskite film forming an encapsulating layer on perovskite nanograin homogeneously. The thin encapsulating network brings much enhanced stability and allows effective carrier transport simultaneously. Light emitting diode based on this composite shows much enhanced stability under continuous operation.

The development of photocatalysts that can effectively harvest visible light is essential for advances in high-efficiency solar-driven hydrogen generation. Herein, we synthesized water soluble CuInS₂ (CIS) and Cu-In-Zn-S (CIZS) quantum dots (QDs) by using one-pot aqueous method. The CIZS QDs are well passivated by glutathione ligands and are highly stable in aqueous conditions. We subsequently applied these QDs as a light harvesting material for photocatalytic hydrogen generation. Unlike most small band gap materials that show extremely low efficiency, these new QDs display remarkable energy conversion efficiency in the visible and near-infrared regions. The external quantum efficiency at 650 nm is ~1.5%, which, to the best of our knowledge, is the highest value achieved until now in the near-infrared region.