Building integrated concentrating photovoltaic (BICPV) windows have attracted numerous studies in recent years. However, there is a tradeoff between the light transmittance and power generation efficiency in the design of BICPV window. In this paper, a smart luminescent solar concentrator (LSC) is introduced as the BICPV window. The proposed smart LSC system features on the combination of fluorescent dyes with thermochromic materials to enhance photoelectric conversion efficiency as well as form a dynamic response mechanism to ambient solar radiation and environmental temperature. In this study, a BICPV smart window system consists of the waveguide doped with organic dye Lumogen F Red-305 (BASF) and the thermochromic hydrogel membrane has been developed. The research on analytic design parameters is executed through optical simulation by ray tracing technology along with outdoor comparative experiments. From simulations for a smart LSC of 100 mm × 100 mm × 3 mm with a bottom-mounted solar cell of 100 mm × 10 mm, the optical effective concentration is found to be with the range of 1.23 to 1.31 when a highest gain of 1.26 in power over the bare solar cell is obtained from experiments.

Switchable multi-layer ethylene tetra-fluoro-ethylene (ETFE) cushion controls the natural light and heat flux passing through the cushion with varying outdoor conditions by dynamically modifying its properties. In this paper, the switchable ETFE cushions with ink printing of different optical and thermal properties were adopted as the window in a typical office model, and the indoor daylight and energy consumption were simulated by using Grasshopper software. Experimental model was built to validate the numerical model. Five locations representing five climate zones in China were selected to analyze the feasibility of the switchable ETFE cushion in different climates. The hourly indoor daylight and heat gain in a single day revealed the effects of the dynamic mechanism of ETFE cushion in improving indoor natural light and thermal environment. In addition, the annual daylight performance at the working area (1.5 m from the window) was simulated. ETFE cushion with printing of the lowest transmittance (ETFE1) was the optimal option for most cities and window-to-wall ratios, with the percentage of annual useful daylight hours up to 78.6%, except for the cases where the window-to-wall ratio (WWR) was 0.35 in Harbin, Beijing, and Hefei. The distribution of useful daylight hours revealed that ETFE cushions with low, medium, and high printing transmittance were suitable for offices where people work in the front, medium, and back region of the room, respectively. Energy consumption calculation revealed that ETFE1 showed advantages over other windows in most cities except for cities highly dominated by heating. ETFE1 delivered up to 33% of energy saving over a year in Kunming compared with the conventional double glazing but was not superior in cities with high heating and low cooling demands, such as Harbin.