In comparison to monolayer (1L), multilayer (ML) two-dimensional (2D) semiconducting transition metal dichalcogenides (TMDs) exhibit more application potential for electronic and optoelectronic devices due to their improved current carrying capability, higher mobility, and broader spectral response. However, the investigation of devices based on wafer-scale ML-TMDs is still restricted by the synthesis of uniform and high-quality ML films. In this work, we propose a strategy of stacking MoS₂ monolayers via a vacuum transfer method, by which one could obtain wafer-scale high-quality MoS₂ films with the desired number of layers at will. The optical characteristics of these stacked ML-MoS₂ films (> 2L) indicate a weak interlayer coupling. The stacked ML-MoS₂ phototransistors show improved optoelectrical performances and a broader spectral response (approximately 300–1,000 nm) than that of 1L-MoS₂. Additionally, the dual-gate ML-MoS₂ transistors enable enhanced electrostatic control over the stacked ML-MoS₂ channel, and the 3L and 4L thicknesses exhibit the optimal device performances according to the turning point of the current on/off ratio and the subthreshold swing.