Facile preparation of additive-free inks with both high viscosity and high conductivity is critical for scalable screen printing of wireless electronics, yet very challenging. MXene materials exhibit excellent conductivity and hydrophilicity, showing great potential in the field of additive-free inks for screen printing. Here, we demonstrate the synthesis of additive-free two-dimensional (2D) titanium carbide MXene inks, and realize screen-printed MXene wireless electronics for the first time. The viscosity of MXene ink is solely regulated by tuning the size of MXene nanosheet without any additives, hence rendering the printed MXene film extremely high conductivity of 1.67 × 10⁵ S/m and fine printing resolution down to 0.05 mm on various flexible substrates. Moreover, radio frequency identification (RFID) tags fabricated using the additive-free MXene ink via screen printing exhibit stable antenna reading performance and superb flexibility. This article, thus offers a new route for the efficient, low-cost and pollution-free manufacture of printable electronics based on additive-free MXene inks.

Conventional glassy carbon electrodes (GCE) cannot meet the requirements of future electrodes for wider use due to low conductivity, high cost, non-portability, and lack of flexibility. Therefore, cost-effective and wearable electrode enabling rapid and versatile molecule detection is becoming important, especially with the ever-increasing demand for health monitoring and point-of-care diagnosis. Graphene is considered as an ideal electrode due to its excellent physicochemical properties. Here, we prepare graphene film with ultra-high conductivity and customize the 3-electrode system via a facile and highly controllable laser engraving approach. Benefiting from the ultra-high conductivity (5.65 × 10⁵ S·m⁻¹), the 3-electrode system can be used as multifunctional electrode for direct detection of dopamine (DA) and enzyme-based detection of glucose without further metal deposition. The dynamic ranges from 1–200 μM to 0.5–8.0 mM were observed for DA and glucose, respectively, with a limit of detection (LOD) of 0.6 μM and 0.41 mM. Overall, the excellent target detection capability caused by the ultra-high conductivity and ease modification of graphene films, together with their superb mechanical properties and ease of mass-produced, provides clear potential not only for replacing GCE for various electrochemical studies but also for the development of portable and high-performance electrochemical wearable medical devices.