Advances in the study of structural ceramic materials have revealed new perspectives and opportunities, with an increasing emphasis on incorporating biomimicry concepts. Carbide ceramics with anisotropic crystal structures—such as silicon carbide—exhibit superior properties, including high modulus, high-temperature resistance, wear resistance, and high thermal conductivity, making them ideal structural materials. The implementation of biomimetic texturing techniques can enhance their performance along specific orientations, thereby expanding their potential for use in more rigorous environments and endowing them with integrated structural and functional characteristics. This review provides an overview of commonly textured biological materials and discusses their performance. It emphasizes the techniques used to prepare anisotropic carbide ceramics and anisotropic carbide ceramic composites—such as strong external field induction (hot working under uniaxial pressure, casting technologies within magnetic alignment, etc.), template methods (biotemplating, ice templating, etc.), and three-dimensional printing technologies (direct ink writing, stereolithography, etc.)—focusing on the work of researchers within the structural ceramic community, summarizing the current challenges in the preparation of anisotropic carbide ceramic composites, and providing insight into their future development and application.
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Poor flowability of printable powders and long preparation cycles are the main challenges in the selective laser sintering (SLS) of chopped carbon fiber (Cf) reinforced silicon carbide (SiC) composites with complex structures. In this study, we develop an efficient and novel processing route in the fabrication of lightweight SiC composites via the SLS of phenolic resin (PR) and Cf powders with the addition of α-SiC particles combined with the one-step reactive melt infiltration (RMI). The effects of α-SiC addition on the microstructural evolution of the Cf/SiC/PR printed bodies, Cf/SiC/C green bodies, and derived SiC composites were investigated. The results indicate that the added α-SiC particles play an important role in enhancing the flowability of raw powders, reducing the porosity, increasing the reliability of the Cf/SiC/C green bodies, and contributing to improving the microstructure homogeneity and mechanical properties of the SiC composites. The maximum density, flexural strength, and fracture toughness (KIC) of the SiC composites are 2.749±0.006 g·cm−3, 266±5 MPa, and 3.30±0.06 MPa·m1/2, respectively. The coefficient of thermal expansion (CTE, α) of the SiC composites is approximately 4.29×10−6 K−1 from room temperature (RT) to 900 ℃, and the thermal conductivity (κ) is in the range of 80.15–92.48 W·m−1·K−1 at RT. The high-temperature strength of the SiC composites increase to 287±18 MPa up to 1200 ℃. This study provides a novel as well as feasible tactic for the preparation of high-quality printable powders as well as lightweight, high-strength, and high–κ SiC composites with complex structures by the SLS and RMI.