The effects of adding pulping black liquor and other additives to coal-water slurry (CWS) on the sulfur-fixing performance of the resultant mixture (pulping black liquor coal-water slurry) were evaluated. The experimental results demonstrated that the ash content of the black liquor coalwater slurry decreased as the addition of pulping black liquor in the mixture increased. Nevertheless, the addition amount should be appropriately selected to ensure that the black liquor coal-water slurry had a moderate calorific value. Addition of black liquor improved the combustion performance of CWS by lowering the ignition point and stabilizing the combustion process; moreover, the sulfur-fixation ratio after combustion increased by 12 to 16 percentage points than that of CWS, and the content of high-melting-point salt in the ash from CWS after adding black liquor was low. The sulfur-fixing ratio of CWS after adding a sulfur-fixing agent was effectively increased by 25 to 30 percenatge points, but with compromise of the fluidity and stability of the CWS; thus, the addition amount of a sulfur-fixing agent should be optimized.