In this study, a straightforward, one-step wet-end formation process was employed to prepare cellulose/graphene conductive paper for antistatic packing materials. Cationic polyacrylamide was introduced into the cellulose/graphene slurry to improve the graphene loading on the surfaces of the cellulose fibers. The effect of the super calender process on the properties of the cellulose/graphene conductive paper was investigated. When 55 wt% graphene was added, the volume resistivity of the cellulose/graphene conductive paper was 94.70 Ω·cm, decreasing to 35.46 Ω·cm after the super calender process. The cellulose/graphene conductive paper possessed excellent anti-static ability and could be used as an anti-static material.