In order to find out the distribution characteristics of BTEX in groundwater, which include Benzene, Toluene, Ethylbenzene, p-Xylene, m-Xylene, and o-Xylene, 82 groups of groundwater samples and 10 surface water samples collected from Guangzhou in Guangdong during 2005 to 2008 were tested by gas chromatography and mass spectrum(GC/MS). The result showed that the BTEX concentration in groundwater does not exceed the standard. The detection rate of BTEX is 14.63% in groundwater, and the total BTEX concentration is lower than 9.5 μg/L. Of 6 kinds of BTEX, toluene had the highest detection rate (12.20%) and detection value (9.5 μg/L), which was followed by Benzene, with the detection rate of 3.65%, and detection value of 4.9 μg/L respectively; most of samples with BTEX are distributed in Huangpu district, Baiyun district, Huadu district and other industrialized areas; this spatial distribution and urban distribution have obvious consistency. With economic development, plant expansion and population growth led to a large amount of waste water discharge, and infrastructure construction is lagging behind, indicating that rapid urbanization is a major driving force of BTEX in groundwater, and through the analysis of a typical area, it is found that benzene system surface water infiltration was an important source of BTEX in groundwater of Guangzhou.

There are a lot of key qualitative variables in factors affecting groundwater vulnerability. The processing of qualitative variables of the existing superimposed index method generally relies on experience, so the results are normally subjective. Quantitative theory can handle qualitative variables quantitatively, achieve the unity of quantitative and qualitative indicators, highlight the decisive role of the main factors and reflect the actual situation more objectively. We took Yulin City as the research area to verify the feasibility and applicability of quantitative theory III, which is used for the quantitative evaluation of groundwater vulnerability. The results show that it has obvious advantage in the screening of indicators and the groundwater vulnerability partition，so it can be used as a quantitative calculation method of groundwater vulnerability assessment.

Precipitation and groundwater are essential to water circulation and they mutually influence. Groundwater is the main water supply source in Hebei Plain. On the other hand, atmospheric precipitation infiltration recharge is the main supply source of the groundwater in this area. Therefore, the studies on Hebei Plain climatic change features are of great significance to further analyze the influences of climatic changes on groundwater resources. This paper selected 10 ground climatological stations in Hebei Plain in terms of daily precipitation and temperature data from 1961 to 2010 and analyzed the spatial-temporal evolution features of temperature and precipitation. The results showed that the minimum temperature of Hebei Plain in recent 50 years increased significantly; the maximum temperature basically is stable; and the mean temperature presents an obviously increasing trend. In the spatial distribution, it gradually decreases from southwest to northeast on the whole and gradually tends to increase from the coastal to inland. The precipitation in recent 50 years owns obvious interannual change features and spatial distribution features, with a trend of overall periodic decrease and significant decrease of extreme precipitation. The annual mean precipitation intensity and annual mean extreme precipitation intensity gradually increased from piedmont plain to coastal plain. Hebei Plain has a warming and drying development trend on the whole. In space, piedmont plain belongs to the high-temperature and few-water area; coastal plain lies in low-temperature and much-water area; and central plain is in transitional zone. The climatic change and human activities are two influential factors of groundwater resources. Further revealing of the climatic change features of different geomorphic types and measuring and distinguishing of the influences of climatic change and human activities on groundwater remain to be further explored.

The groundwater in the research area is characterized by alkalescence, generally over-high EC value, and relatively low dissolved oxygen and oxidation-reduction potential. The pollution is presented by abnormal acid-base, dissolved oxygen reduction, and conductivity rise. The overall situation of groundwater chemical field is controlled by natural conditions, the hydrochemical type has obvious zoning feature and changes from single type to multiple types from the river bank of the Yellow River to both sides, and the local abnormality is closely related to the intensity of human activities. The pollution scope and degree of inorganic toxicological indexes and organic indexes are strongly correlated with land utilization type, pollution source distribution, urbanization, and pollutant disposal of the city, the pollution in the petrochemical industrial area is the most serious, and the organic pollution tends to escalate and diffuse to the downstream.