In this work, we proposed a method for coating the whole surfaces of bearing balls uniformly by carbon film with a rotatable ball clamp. We studied the carbon/carbon friction with a self-designed current- carrying ball bearing friction test system. A notable and instant friction force drop of 28% and significant carbon film wear alleviation were found when currents were applied. By using TEM-, SEM-, and EDS-analysis, special carbon stacks with a mixture of large wear particles and oxide were found in the wear areas under current applied condition. We elucidated the current-carrying friction mechanisms as follows: (1) wear particles formation; (2) wear particles charged by tribomicroplasma; (3) formation of surface passivated carbon stacks under electric force; (4) sliding between passivated carbon surfaces. This work may facilitate the development of novel solid-lubricated ball bearings and lay some foundations for current-carrying rolling friction.