When deploying workflows in cloud environments, the use of Spot Instances (SIs) is intriguing as they are much cheaper than on-demand ones. However, SIs are volatile and may be revoked at any time, which results in a more challenging scheduling problem involving execution interruption and hence hinders the successful handling of conventional cloud workflow scheduling techniques. Although some scheduling methods for SIs have been proposed, most of them are no more applicable to the latest SIs, as they have evolved by eliminating bidding and simplifying the pricing model. This study focuses on how to minimize the execution cost with a deadline constraint when deploying a workflow on volatile SIs in cloud environments. Based on Monte Carlo simulation and list scheduling, a stochastic scheduling method called MCLS is devised to optimize a utility function introduced for this problem. With the Monte Carlo simulation framework, MCLS employs sampled task execution time to build solutions via deadline distribution and list scheduling, and then returns the most robust solution from all the candidates with a specific evaluation mechanism and selection criteria. Experimental results show that the performance of MCLS is more competitive compared with traditional algorithms.