Global warming caused by excess carbon dioxide (CO₂) emission has been a focus of the world. The development of neutral carbon technologies becomes a strategic choice for the sustainable human society. Integrating CO₂ capture and conversion (iCCC) technology can simultaneously convert the captured CO₂ from flue gas into value-added chemicals, which saves great energies and expenses incurred in CO₂ compression and transportation processes of conventional carbon capture, utilization, and storage (CCUS) technology. The present review critically discusses the dual-function materials (DFMs) and the iCCC technology at intermediate temperature for methane production and high temperature for syngas production. The design of reactor and optimization of operation conditions are emphasized from the perspective of industrial applications. The dual-fixed-bed reactors mode by switching the flue gas and reactant gases, and the dual-fluidized-bed reactors mode by the circulation of DFMs particles are comparatively reviewed. We hope this review can stimulate further studies including designing and fabricating feasible DFMs, exploring realistic catalytic process for CO₂ conversion to high value-added chemicals, developing workable reactor modes and optimizing operation conditions, and establishing industrial demonstration for real applications of iCCC technology in the future.