Stimulus-responsive polymers have steadily grown in significance over the past few decades, with extensive research dedicated to the intelligent design of friction materials inspired by natural processes. In this study, we introduce a hydrogel system, CS-MXene@P(AAc-CaAc-co-HEMA-Br)@PSPMA (M-PAAc@PSPMA), that adeptly modulates its modulus across temperature variations, subsequently influencing the interface friction coefficient. The integration of CS-MXene as a photothermal agent facilitates interface temperature modulation under near-infrared (NIR) light irradiation. By manipulating the temperature, the modulus of the P(AAc-CaAc-co-HEMA-Br) hydrogel can be effectively regulated. Moreover, the poly(3-sulfopropyl methacrylate potassium) (PSPMA) polyelectrolyte brush further refines the lubricating attributes of the system. Under ambient conditions, the hydrogel is characterized by a low modulus, heightened flexibility, diminished strength, and a friction coefficient of approximately 0.24. In contrast, under NIR irradiation, the modulus, hardness, and strength of the hydrogel increased, and the friction coefficient decreased to approximately 0.1. This innovative hydrogel system offers advanced friction control by modulating its modulus, setting a precedent for the future development of intelligent lubricant hydrogels, interface detection, and regulated transmission.

In response to the ongoing energy crisis, advancing the field of electrocatalytic water splitting is of utmost significance, necessitating the urgent development of high-performance, cost-effective, and durable hydrogen evolution reaction catalysts. But the generated gas bubble adherence to the electrode surface and sluggish separation contribute to significant energy loss, primarily due to the insufficient exposure of active sites, thus substantially hindering electrochemical performance. Here, we successfully developed a superaerophobic catalytic electrode by loading phosphorus-doped nickel metal (NiP_x) onto various conductive substrates via an electrodeposition method. The electrode exhibits a unique surface structure, characterized by prominent surface fissures, which not only exposes additional active sites but also endows the electrode with superaerophobic properties. The NiP_x/Ti electrode demonstrates superior electrocatalytic activity for hydrogen evolution reaction, significantly outperforming a platinum plate, displaying an overpotential of mere 216 mV to achieve a current density of −500 mA cm⁻² in 1 M KOH. Furthermore, the NiP_x/Ti electrode manifests outstanding durability and robustness during continuous electrolysis, maintaining stability at a current density of −10 mA cm⁻² over a duration of 2000 h. Owing to the straightforward and scalable preparation methods, this highly efficient and stable NiP_x/Ti electrocatalyst offers a novel strategy for the development of industrial water electrolysis.