Preparation and Luminescence of MgO-BaO-SiO2 Glass Doped with Ce:YAG for White Light Laser Diode
), Hongbo DONG2()Abstract
Blue laser diode (LD) combined with appropriate phosphors have been recognized as next generation solid white lighting technology. The conventional silicone package LD has the problem of efficiency droop, limiting the application in high power field. In this work, glass phosphors were developed by using MgO-BaO-SiO2 as the glass matrix and Ce:YAG as phosphor. The glass phosphors were integrated with 450 nm LD chip for white light emission. Phase composition and microstructure of the glass phosphors were systematically studied, while their luminescent performances were evaluated and discussed. Luminescent parameters, including luminous efficiency of 125.31 lm·W−1, correlated color temperature of 5286 K and CIE coordinates of (0.33, 0.33), were achieved in the sample with 12 wt.% Ce:YAG. These glass phosphors could find potential applications for high power white lighting.
References
HE Y, LIU K G, XIAO Z H, et al. Applications of transparent ceramics in solid state lighting [J]. Journal of Ceramics, 2021, 42(1): 21–35 (In Chinese).
NAKAMURA S, MUKAI T, SENOHM. Candela‐class high‐brightness InGaN/AlGaN double‐heterostructure blue‐light‐emitting diodes [J]. Applied Physics Letters, 1994, 64(13): 1687–1689.
YAM F K, HASSAN Z. Innovative advances in LED technology [J]. Microelectronics Journal, 2005, 36(2): 129–137.
WANG P F, SUI P, LIN S S, et al. Lu2SrAl4SiO12Ce3+ phosphor in glass film-on-sapphire and its application to laser lighting [J]. Chinese Journal of Luminescence, 2021, 42(10): 1493–1501 (In Chinese).
YAN C, DING X, CHEN M, et al. Research on laser illumination based on phosphor in metal (PIM) by utilizing the boron nitride-coated copper foams [J]. ACS Applied Materials & Interfaces, 2021, 13(25): 29996–30007.
KINOSHITA J, IKEDA Y, TAKEDA Y, et al. Suppressed speckle contrast of blue light emission out of white lamp with phosphors excited by blue laser diodes for high-brightness lighting applications [J]. Optical Review, 2012, 19: 427–431.
MUELLER-MACH R, MUELLER G, KRAMES M R, et al. Highly efficient all-nitride phosphor-converted white light emitting diode [J]. Applications and Materials Science, 2005, 202(9): 1727–1732.
CHO J, SCHUBERT E F, KIM J K. Efficiency droop in light-emitting diodes: Challenges and countermeasures [J]. Laser & Photonics Reviews, 2013, 7(3): 408–421.
BERGH A A. Blue laser diode (LD) and light emitting diode (LED) applications [J]. Physica Status Solidi, 2004, 201(12): 2740–2754.
GONDA S I, TSUTSUMI H, ITO Y, et al. Proton radiation effects in nitride lasers and light emitting diodes [J]. Physica Status Solidi, 2007, 204(1): 231–235.
KOJIMA K, FUNATO M, KAWAKAMI Y, et al. Comparison between optical gain spectra of InxGa1−xN/In0.02Ga0.98N laser diodes emitting at 404 nm and 470 nm [J]. Physica Status Solidi, 2007, 204(6): 2108–2111.
LI D S, SHI W, LIU X F, et al. Progress of research for laser driven white light and analysis of its key technologies [J]. Laser Journal, 2015, 36(7): 1–4.
TSAO J Y. Solid-state lighting lamps, chips and materials for tomorrow [J]. IEEE Circuits and Devices Magazine, 2004, 20(3): 28–37.
BEARD M C, LUTHER J M, NOZIK A J. The promise and challenge of nanostructured solar cells [J]. Nature Nanotechnology, 2014, 9(12): 951–984.
STEIGERWALD D A, BHAT J C, COLLINS D, et al. Illumination with solid state lighting technology [J]. IEEE Journal of Selected Topics in Quantum Electronics, 2002, 8(2): 310–320.
YAO G Q, DUAN J F, REN M, et al. Preparation and luminescence of blue light conversion material YAG:Ce [J]. Chinese Journal of Luminescence, 2001, 22(S1): 21-23 (In Chinese).
ZHENG R L. Development of Yb3+-doped fluorophosphate laser glass [J]. Guangdong Chemical Industry, 2014, 41(21): 92–93 (In Chinese).
DING H, HU P, LIU Y F, et al. Recent progress of LuAG:Ce3+ for white laser diode lighting application [J]. Chinese Journal of Luminescence, 2021, 42(10): 1531–1548 (In Chinese).
HU P, DING H, LIU Y F, et al. Recent progress of YAG:Ce3+ for white laser diode lighting application [J]. Chinese Journal of Luminescence, 2020, 41(12): 1504–1528 (In Chinese).
LI H Y, LI G, ZHOU J S, et al. Preparation and properties of low melting temperature phosphor glass thick films for white LEDs [J]. Journal of Ceramics, 2018, 39(3): 302–305 (In Chinese).
XU M, TANG G, SHI H S, et al. Preparation and characterization of phosphor-on-glass (PoG) materials for white LEDs [J]. Journal of Synthetic Crystals, 2019, 48(7): 1218–1224 (In Chinese).
JIANG Y G, JIANG B X, YUAN X Q, et al. Preparation and luminescence of Ce:YAG transparent glass ceramics by liquid-phase sintering [J]. Materials Letters, 2017, 195: 120–122.
YAO Q, HU P, SUN P, et al. YAG:Ce3+ transparent ceramic phosphors brighten the next-generation laser-driven lighting [J]. Advanced Material, 2020, 32(19): e1907888.
YUE X M, LIN H, LIN S S, et al. La3Si6N11:Ce3+ luminescent glass ceramics applicable to high-power solid-state lighting [J]. Chinese Journal of Luminescence, 2020, 41(12): 1529–1537 (In Chinese).
YU J D, YU S D, FU T, et al. Micro-prism patterned remote phosphor film for enhanced luminous efficiency and color uniformity of phosphor-converted light-emitting diodes [J]. Micromachines, 2021, 12(9): 1117.
ZUO C H, LU A X, XIAO Z H, et al. Luminescent properties of Ce3+ and Tb3+ doped BaO-La2O3-B2O3-SiO2 glasses [J]. Journal of Central South University Science and Technology, 2009, 40(6): 1522–1528 (In Chinses).
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