The Marangoni effect assumes significance in bubbly flows when temperature or concentration gradients exist in the domain. This study investigated the hydrodynamics of single bubbles under the influence of the Marangoni force induced by stratified fields of dissolved sugar, providing a numerical framework for examining these phenomena. A laboratory-scale bubble column and high-speed imaging were utilized to analyze the bubble behavior. The OpenFOAM-based geometric volume of the fluid solver was extended by incorporating the solutocapillary Marangoni effect, and a passive scalar transport equation for the sugar concentration was solved. The results revealed that small bubbles entering regions with elevated sugar concentrations experienced deceleration, transitioning into linear paths, while those departing from regions with high sugar concentrations exhibited fluctuations and meandering. Furthermore, the concentration gradient leads larger bubbles to meander throughout the entire column, without a notable increase in their velocity. The intensity of these behaviors is governed by the magnitude of the Marangoni force. The findings provide a better understanding of single bubble hydrodynamics in complex environments.

Reactive bubble columns are omnipresent in the chemical industry. The layout of these columns is still limited by correlations and therefore improved simulation techniques are required to describe the complex hydrodynamics/reaction interaction. In this work, we focus on the numerical and experimental study of the viscosity influence on bubble motion and reaction using an Euler-Lagrange framework with an added oscillation and reaction model to bring the column layout base closer to a predictive level. For comparison and validation, experimental data in various water-glycerol solutions was obtained in a cylindrical bubble column at low gas hold-up, where the main parameters such as bubble size, motion, and velocities were detected. Glycerol leads thereby to a change in viscosity and surface tension. Further, the surface tension was modified by addition of a surfactant. The bubble oscillating motion in low to higher viscosity could be described using an Euler-Lagrange framework and enables a description of industrial bubble flows. In addition, the simulations were in good agreement concerning reactive mass transfer investigations at higher viscosity of the liquid which led to an overall lower mass transfer compared to the cases with lower viscosity.