As drilling wells continue to move into deep ultra-deep layers, the requirements for temperature resistance of drilling fluid treatments are getting higher and higher. Among them, blocking agent, as one of the key treatment agents, has also become a hot spot of research. In this study, a high temperature resistant strong adsorption rigid blocking agent (QW-1) was prepared using KH570 modified silica, acrylamide (AM) and allyltrimethylammonium chloride (TMAAC). QW-1 has good thermal stability, average particle size of 1.46 μm, water contact angle of 10.5°, has a strong hydrophilicity, can be well dispersed in water. The experimental results showed that when 2 wt% QW-1 was added to recipe A (4 wt% bentonite slurry+0.5 wt% DSP-1 (filtration loss depressant)), the API filtration loss decreased from 7.8 to 6.4 mL. After aging at 240 ℃, the API loss of filtration was reduced from 21 to 14 mL, which has certain performance of high temperature loss of filtration. At the same time, it is effective in sealing 80–100 mesh and 100–120 mesh sand beds as well as 3 and 5 μm ceramic sand discs. Under the same conditions, the blocking performance was superior to silica (5 μm) and calcium carbonate (2.6 μm). In addition, the mechanism of action of QW-1 was further investigated. The results show that QW-1 with amide and quaternary ammonium groups on the molecular chain can be adsorbed onto the surface of clay particles through hydrogen bonding and electrostatic interaction to form a dense blocking layer, thus preventing further intrusion of drilling fluid into the formation.

During ultradeep oil and gas drilling, fluid loss reducers are highly important for water-based drilling fluids, while preparing high temperature- and salt-resistance fluid loss reducers with excellent rheology and filtration performance remains a challenge. Herein, a micro-crosslinked amphoteric hydrophobic association copolymer (i.e., DADC) was synthesized using N,N-dimethyl acrylamide, diallyl dimethyl ammonium chloride, 2-acrylamido-2-methylpropane sulfonic acid, hydrophobic monomer, and pentaerythritol triallyl ether crosslinker. Due to the synergistic effects of hydrogen bonds, electrostatic interaction, hydrophobic association, and micro-crosslinking, the DADC copolymer exhibited outstanding temperature- and salt-resistance. The rheological experiments have shown that the DADC copolymer had excellent shear dilution performance and a certain degree of salt-responsive viscosity-increasing performance. The DADC copolymer could effectively adsorb on the surface of bentonite particles through electrostatic interaction and hydrogen bonds, which bring more negative charge to the bentonite, thus improving the hydration and dispersion of bentonite particles as well as the colloidal stability of the drilling fluids. Moreover, the drilling fluids constructed based on the DADC copolymer exhibited satisfactory rheological and filtration properties (FL_HTHP = 12 mL) after aging at high temperatures (up to 200 ℃) and high salinity (saturated salt) environments. Therefore, this work provided new insights into designing and fabricating high-performance drilling fluid treatment agents, demonstrating good potential applications in deep and ultradeep drilling engineering.

Ocean gas hydrate is a potentially efficient and clean oil and gas alternative energy resource. Wells with complex structure, such as horizontal wells, can improve the extraction efficiency; however, drilling operations face challenges such as wellbore instability and reservoir damage due to the complex interaction between drilling fluids and hydrate reservoirs. This work presents a ceramsite temporary plugging microcapsule that uses ceramsite modified by 3-aminopropyltriethoxysilane as the core material and chitosan and sodium alginate as shell materials. It exhibits high strength during drilling and excellent plugging effects. After the action of bioenzymes, it can easily be dissolved, leading to high permeability post-drilling. The analysis and performance evaluation of ceramsite microcapsules show that their particle size is generally 40 μm, which can match the pore size of the hydrate reservoir depending on the number of encapsulation layers. Bioenzyme optimization at 15 ℃ yields the best permeability recovery of 74.5% for the low-temperature composite enzyme. As the temperature rises, the permeability recovery rate of ceramic microcapsules gradually increases and the difference in permeability recovery rate between 5 and 25 ℃ becomes more significant. With a longer degradation time, the permeability recovery rate of ceramsite microcapsules gradually enhances and the difference in permeability recovery rate becomes smaller after 12 h. The microcapsules exhibit a specific inhibitory effect on the decomposition of hydrates. Utilizing bioenzyme-responsive ceramsite microcapsules as temporary plugging materials can establish an “isolation barrier” around the wellbore, effectively sealing off the interaction between the wellbore and the gas hydrate reservoir during the drilling process. Re-opening the flow path around the well by bio-enzymatic unblocking at the end of drilling proves to be effective in solving the problem of balancing the stability of the well wall and protecting the reservoir.

Natural gas hydrate reservoirs in the northern South China Sea primarily comprise clayey silt, making exploitation more challenging relative to sandy reservoirs in other countries and regions. This paper provides an overview of the latest research developments in the exploitation mechanism covering the past five years, focusing on hydrate phase transition, multiphase flow in the decomposition zone, the seepage regulation of reservoir stimulation zone, and production capacity simulation, all of which are relevant to the previously conducted two rounds of hydrate trial production in offshore areas of China. The results indicate that the phase transition of clayey-silt hydrate remains in a dynamic equilibrium, with the decomposition efficiency mainly controlled by the coupling of heat and flow and high heat consumption during decomposition. The decomposition zone exhibits strong hydrophilicity, easy adsorption, and sudden permeability changes. A temperature drop is present that is concentrated near the wellbore, and once a water lock has formed, the gas-phase flow capacity significantly decreases, leading to potential secondary hydrate formation. To enhance permeability and increase production, it is imperative to implement reservoir and temperature field reconstruction based on initial formation alterations, which will further optimize and improve the transport capacity of the reservoir.

Lost circulation is a common and complex downhole accident in the process of oil and gas drilling. Traditional bridge plugging material has the limitation of poor adaptability to lost formations. Therefore,this study synthesized a new self-healing plugging material to improve the plugging success rate; specifically,the hydrophobic association polymer lauryl methlacrylate-acrylamide-acrylic acid containing Fe³⁺ was modified via curdlan to form a composite gel with high strength and self-healing properties. The self-healing time,mechanicalness and rheological properties of the self-healing gel were systematically evaluated. The results showed that the modification of curdlan could significantly improve the mechanical properties and rheological strength of self-healing gel,and the chelating structure formed by Fe³⁺ and carboxyl groups could further enhance the mechanical properties of the self-healing gel. Toughness and storage modulus of the LF_0.15C₂ self-healing gel with the introduction of curdlan and Fe³⁺ could reach 30.2 kJ/m³ and 3,458 Pa,respectively. Compared with conventional gel materials,composite gels with self-healing properties exhibited better pressure-bearing capacity of 2.5 MPa,and could effectively avoid causing plugging at the entrance of the fractures by high-concentration inert material and improve the pressure-bearing capacity. In addition,the plugging mechanism of the self-healing gel modified via curdlan in formation fractures was analysed in detail. The self-healing gel modified via curdlan prepared in this work has application potential as a lost circulation material in the field of oil and gas drilling.