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A self-healing aqueous ammonium-ion micro batteries based on PVA-NH4Cl hydrogel electrolyte and MXene-integrated perylene anode
Nano Research Energy
Published: 03 June 2024
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The successful study of self-healing aqueous micro batteries (AMBs) which inherit the advantages of aqueous batteries and have the ability to automatically repair damage is of great significance for the development of smart wearable and portable electronic devices. However, the rate performance and the related power density of developed self-healing AMBs using metal ions as charge carriers is limited, due to the strong interaction between metal ions and electrode materials. Therefore, there is great potential for developing self-healing NH4+ AMBs, because of the outstanding advantages of NH4+ such as extremely abundant reserves, smaller hydrated ion radius and little molar mass. However, the development of self-healing NH4+ AMBs is still an extremely challenge due to the difficulty in developing self-healing hydrogels and instability of anode materials. Even though, the firstly self-healing NH4+ AMBs based on tailoring hydrogel electrolyte and MXene-integrated perylene anode were successfully assembled. As expected, self-healing NH4+ AMBs exhibit excellent energy density (82.48 µWh·cm−2) and power density (3.09 mW·cm−2), cycle life (81.67% after 3000 GCD cycles), flexibility (95.68% under 180°) and self-healing ability (94.16% after the 10th self-healing cycles).

Open Access Research Article Issue
Boron nitride microribbons strengthened and toughened alumina composite ceramics with excellent mechanical, dielectric, and thermal conductivity properties
Journal of Advanced Ceramics 2024, 13(4): 496-506
Published: 30 April 2024
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Downloads:384

Aluminum oxide (Al2O3) ceramics have been widely utilized as circuit substrates owing to their exceptional performance. In this study, boron nitride microribbon (BNMR)/Al2O3 composite ceramics are prepared using spark plasma sintering (SPS). This study examines the effect of varying the amount of toughened phase BNMR on the density, mechanical properties, dielectric constant, and thermal conductivity of BNMR/Al2O3 composite ceramics while also exploring the mechanisms behind the toughening and increased thermal conductivity of the fabricated ceramics. The results showed that for a BNMR content of 5 wt%, BNMR/Al2O3 composite ceramics displayed more enhanced characteristics than pure Al2O3 ceramics. In particular, the relative density, hardness, fracture toughness, and bending strength were 99.95%±0.025%, 34.11±1.5 GPa, 5.42±0.21 MPa·m1/2, and 375±2.5 MPa, respectively. These values represent increases of 0.76%, 70%, 35%, and 25%, respectively, compared with the corresponding values for pure Al2O3 ceramics. Furthermore, during the SPS process, BNMRs are subjected to high temperatures and pressures, resulting in the bending and deformation of the Al2O3 matrix; this leads to the formation of special thermal pathways within it. The dielectric constant of the composite ceramics decreased by 25.6%, whereas the thermal conductivity increased by 45.6% compared with that of the pure Al2O3 ceramics. The results of this study provide valuable insights into ways of enhancing the performance of Al2O3-based ceramic substrates by incorporating novel BNMRs as a second phase. These improvements are significant for potential applications in circuit substrates and related fields that require high-performance materials with improved mechanical properties and thermal conductivities.

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