Understanding the wetting behaviors of droplets on grooved surfaces is indispensable in surface science and offers promising avenues for advancing industrial processes. The droplet spreading on grooved surfaces can be discretized into a series of individual events that the droplet across each groove with variations in capillary forces and a subsequent re-equilibrium. In this work, a simplified model of droplet spreading on surface with an individual groove on both the left and right sides was utilized in order to elucidate the fundamental mechanisms underlying contact line pinning due to the groove. We examined the effects of the groove position and the wettability of solid surfaces. The contact line is observed to be pinned when the grooves are strategically positioned. However, by reducing the distance between the grooves, the contact lines can cross them. In such instances, the spreading process can be classified into four modes: Free spreading, impeding spreading, pinning, and depinning. The pinning and depinning phenomenon are explained by the balance between the driving force and pinning force on the contact line. Based on simulation results, the maximum pinning force exerted on the contact line by a certain solid surface can be theoretically predicted. Besides, the wettability of the solid surface also contributes to the impeding effect. This work provides theoretical guidance for the study of wetting on grooved surfaces at the nanoscale, which is essential for developing a comprehensive understanding of the interactions between droplets and structured surfaces, with potential applications in optimizing industrial processes and advancing surface science.

Interactions at the oil/brine/rock interfaces play a pivotal role in the mobility of crude oil within reservoir matrices. Unraveling the microscopic mechanisms of these interactions is crucial for ion-engineered water flooding in secondary and tertiary oil recovery. In this study, the occurrence and transport behavior of crude oil in kaolinite nanopores covered with thin brine films was investigated by molecular dynamics simulation. There is an apparent interface layered phenomenon for the liquid molecules in slit pores and the polar oil components primarily concentrate at the oil/brine interfacial region and form various binding connections with ions. The interfacial interactions between the polar oil components and brine ions exhibit an inhibitory effect on the transport of crude oil through nanopores. The interaction mechanism between acetic acid molecules and hydrated ions was elucidated by interaction modes and interaction intensity, which was proved to illustrate the flow difference in different brine film systems. Moreover, a strategy of exchanging the binding sites of divalent cations with acetic acid molecules by monovalent cations with a higher concentration was proposed. The cation exchange scheme was further validated, demonstrating an enhancement in the oil mobility within nanopores. These findings deepen our understanding of oil/brine/rock interfacial interactions and provide a significant molecular perspective on ion-engineered water flooding for enhanced oil recovery.