With the global population growing, energy demand has increased drastically. Simultaneously, environmental concerns have been increasing at an alarming rate. In transportation systems such as pipelines and ships, the resistance caused by friction is a major factor leading to energy loss. This not only leads to high energy consumption but also hinders improving the overall efficiency of transportation processes. Therefore, finding a solution to minimize this energy loss has emerged as a critical research area among scholars. A viable solution inspired by the unique structures in nature is deemed an effective drag reduction method. This paper outlines the bionic structures of earthworms, sharks, and dolphins and discusses their theory and mechanism for reducing drag. Furthermore, this paper compares recent approaches employing bionic drag–reduction interfaces based on earthworm, shark, and dolphin body structures. The applications of bionic interfacial drag reduction materials in agriculture, transportation, and industry are also analyzed, along with a summary of the limitations and challenges associated with bionic interfacial drag reduction. Finally, the authors look forward to future research directions and application prospects of bionic interfacial drag reduction materials.
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Friction phenomenon is deeply affected by interfacial mechanical and tribo-chemical effects which contain major factors such as loads, sliding rates, sliding time, humidity, temperature and oxide films. For practical applications at different vacuum levels, friction mechanisms (adhesive wear, abrasive wear, fatigue wear, corrosive wear and micromotor wear) are of great importance to develop advanced materials with desirable tribological properties to promote vacuum tribology. In this review, combining current understanding of friction-wear interactions, the tribological phenomena caused by changes on the surfaces of friction pairs and highly dependent on the complex conditions in different vacuum environments are analyzed and summarized. Subsequently, protection strategies for different structural materials are summarized. Finally, this work provides the outlook for designing advanced and sustainable protective materials under different vacuum conditions.
The lack of fresh water resources is a problem that the world is struggling with. Fast and efficient water capture from fog is a good solution for many organisms living in arid regions. SLIPS surfaces exhibit excellent droplet transport and shedding properties with very low sliding angles compared to superhydrophobic surfaces. It is not easy to produce water film, which can effectively improve the efficiency of fog collection. The shape and size of the micro-nano structure are flexibly adjusted by laser etching, uniformly cover the nanowires on the micron-scale pillars and groove structure by ammonia etching, and inject silicone oil by spin-coating to obtain the slippery liquid infused surface with micro-nano structure. Under the synergistic effect of our constructed micro-nano structure, the superhydrophobic surface injected with lubricant exhibits efficient droplet capture, aggregation and removal properties, which greatly improves the fog collection efficiency (107% higher than the original sample). More importantly, the surface has excellent stability, ice resistance and acid/alkali resistance, which is expected to be used in various extreme adjustments.
Untethered and self-transformable miniature robots are capable of performing reconfigurable deformation and on-demand locomotion, which aid the traversal toward various lumens, and bring revolutionary changes for targeted delivery in gastrointestinal (GI) tract. However, the viscous non-Newtonian liquid environment and plicae gastricae obstacles severely hamper high-precision actuation and payload delivery. Here, we developed a low-friction soft robot by assembly of densely arranged cone structures and grafting of hydrophobic monolayers. The magnetic orientation encoded robot can move in multiple modes, with a substantially reduced drag, terrain adaptability, and improved motion velocity across the non-Newtonian liquids. Notably, the robot stiffness can be reversibly controlled with magnetically induced hardening, enabling on-site scratching and destruction of antibiotic-ineradicable polymeric matrix in biofilms with a low-frequency magnetic field. Furthermore, the magnetocaloric effect can be utilized to eradicate the bacteria by magnetocaloric effect under high-frequency alternating field. To verify the potential applications inside the body, the clinical imaging-guided actuation platforms were developed for vision-based control and delivery of the robots. The developed low-friction robots and clinical imaging-guided actuation platforms show their high potential to perform bacterial infection therapy in various lumens inside the body.
Oil pollution and the energy crisis make oil-water separation an urgent for human need. The widespread use of materials with a single emulsion separation capability is limited. Multifunctional on-demand separation materials can adapt to a wide range of application scenarios, thus having a wider range of applications. The underoil superhydrophilic surface is of great significance for realizing the on-demand separation of oil/water emulsions through the removal of water in the oil and oil in the water. A 3D porous emulsion separation material based on the superhydrophilic principle of sphagnum moss was designed. The material was prepared in a simple step by taking advantage of the adhesion of polydopamine and the introduction of the as-prepared superhydrophilic BaSO4 nanoparticles to achieve superhydrophilicity with a water contact angle (WCA) of 0° and an oil contact angle (OCA) of 157.3°, resulting in excellent separation performance for both water-in-oil and oil-in-water emulsions. Underoil superhydrophilic porous composite (OSPC) can complete two kinds of emulsion separations by filtration or adsorption. It adsorbs water from water-in-oil emulsion to achieve separation, with a good adsorption capacity of 74.38 g/g and efficiency up to 99%. It can also filter oil-in-water emulsions with an efficiency of 99.92%. The separation efficiencies are all almost unchanged after ten separation cycles. Furthermore, the material has excellent flame retardancy, which reduces the possibility of secondary disasters. The three-dimensional porous sponge has excellent on-demand separation performance for multiple emulsions. It provides a new preparation strategy for underoil superhydrophilic materials and a new idea for the design direction of special wetting materials for the on-demand separation of oil/water emulsions.
The separation of oil-in-water emulsion is an urgent challenge because its massive production and discharge from daily and industrial activities have caused severe hazards to the ecosystem and serious threats to human health. Membrane technology is considered an outstanding solution strategy for the separation of oil-in-water emulsions due to its unique advantages of low cost, high efficiency, easy operation, and environmental friendliness. However, the membrane is easily fouled by the emulsion oil droplets during the separation process, causing a sharp decline in permeation flux, which greatly inhibits the long-term use of the membrane and largely shortens the membrane’s life. Recently, it was found that endowing the membranes with special wettability e.g., superhydrophilic and superoleophobic can greatly enhance the permeability of the continuous water phase and inhibit the adhesion of oil droplets, thus promoting the separation performance and anti-oil-fouling property of membrane for oily emulsions. In this paper, we review and discuss the recent developments in membranes with special wettability for separating oil-in-water emulsions, including the mechanism analysis of emulsion separation membrane, membrane fouling issues, design strategies, and representative studies for enhancing the membrane’s anti-oil-fouling ability and emulsion separation performance.
Lubricants are often contaminated by water in different ways. Water-polluted lubricants extremely accelerate wear corrosion, leading to the deterioration of lubricity performance. Recently, multiphase media superwettability has been developed to endow one surface with compatible functions, such as on-demand separation of oily wastewater. However, realizing the robustness of the dual superlyophobic surface to solve water-caused lubricant deterioration and water contamination as needed remains challenges. Herein, a robust dual superlyophobic membrane is presented to realize on-demand separation for various lubricant–water emulsions. Compared to pure lubricants, the purified lubricants have equivalent tribology performance, which are much better than that of water-polluted lubricants. The as-prepared membrane maintains dual superlyophobicity, high-efficient for water or lubricant purification, and excellent tribology performance of the purified lubricant, even after immersion in hot liquids for 24 h, multicycle separation, and sandpaper abrasion for 50 cycles. Water-polluted lubricant extremely accelerates wear corrosion to promote catalytic dehydrogenation of lubricants, generating too much harmful carbon-based debris. This work shows great guiding significance for recovering the tribology performance of water-polluted lubricants and purifying water by the dual superlyophobic membrane.
The issues regarding energy dissipation and component damage caused by the interface friction between a friction pair attract enormous attention to friction reduction. The key-enabling technique to realize friction reduction is the use of lubricants. The lubricants smooth the contact interfaces, achieving an ultralow friction contact, which is called superslippery or superlubricity. At present, superslippery and superlubricity are two isolated research topics. There is a lack of unified definition on superslippery and superlubricity from the viewpoint of tribology. Herein, this review aims at exploring the differences and relations between superslippery and superlubricity from their origin and application scenarios. Meanwhile, the challenges for developing superslippery surface and superlubricity surface are discussed. In addition, perspectives on the interactive development of these two surfaces are presented. We hope that our discussion can provide guidance for designing superslippery or superlubricity surfaces by using varies drag-reduction technologies.
Triboelectric nanogenerator (TENG) based on triboelectrification has attracted wide attention due to its effective utilization of green energy sources such as marine energy. However, researches about liquid–liquid triboelectrification are still scanty as solid–liquid triboelectrification has been widely studied. Herein, this work focuses on the hydrophobic/slippery substrate–water interfacial triboelectrification based on the solid friction materials of polytetrafluoroethylene (PTFE) nanoparticles. The hydrophobic/slippery substrate–water interfacial triboelectrification are studied by assembling PTFE coated Al sheets and perfluoropolyether (PFPE) infused PTFE coated Al sheets (formed the slippery lubricant-infused surfaces (SLIPSs)) as the friction electrode, and water as liquid friction materials, respectively. The results show that the hydrophobic TENG output performances improved as the PTFE nanoparticles cumulating, and the SLIPSs TENG output performances increased with the thinner PFPE thickness. Both the triboelectrification behavior of hydrophobic/SLIPSs TENG assembled in this work are dominated by the electron transfer. Thanks to the introduction of SLIPSs, the SLIPSs TENG exhibits superior stability and durability than the hydrophobic TENG. The investigation of hydrophobic/slippery substrate–water interfacial triboelectrification contributes to optimize the TENG performances, and expands the application in harsh environments including low temperature and high humidity on the ocean.
Slippery lubricant-infused surfaces exhibit excellent fog-harvesting capacities compared with superhydrophobic and superhydrophilic surfaces. However, lubricant depletion is typically unavoidable under dynamic conditions, and reinfused oil is generally needed to recover the fog-harvesting capacity. Herein, an effective strategy for delaying the depletion of lubricant to prolong the service life of fog harvesting is proposed. An ultrathin transparent lubricant self-replenishing slippery surface was fabricated via facile one-step solvent evaporation polymerization. The gel film of the lubricant self-replenishing slippery surface, which was embedded with oil microdroplets, was attached to glass slides via the phase separation and evaporation of tetrahydrofuran. The gel film GFs-150 (with oil content 150 wt% of aminopropyl-terminated polydimethyl siloxane (PDMS–NH2)) exhibited superior slippery and fog-harvesting performance to other gel films. Furthermore, the slippery surfaces with the trait of oil secretion triggered by mechanical stress exhibited better fog-harvesting capabilities and longer service life than surfaces without the function of lubricant self-replenishment. The lubricant self-replenishing, ultrathin, and transparent slippery surfaces reported herein have considerable potential for applications involving narrow spaces, visualization, long service life, etc.